Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units

Alexander L. Kanibolotsky; Lyudmila Kanibolotskaya; Sergey Gordeyev; Peter J. Skabara; Iain McCulloch; Rory Berridge; Jan E. Lohr; Filippo Marchioni; Fred Wudl

doi:10.1021/ol070366h

Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units

Alexander L. Kanibolotsky, Lyudmila Kanibolotskaya, Sergey Gordeyev, Peter J. Skabara, Iain McCulloch, Rory Berridge, Jan E. Lohr, Filippo Marchioni, Fred Wudl

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Equation presented We report the synthesis of a novel end-capped sexithiophene derivative bearing two pendent, fused tetrathiafulvalene (TTF) units linked to the main chain through 1,4-dithiin heterocycles. Cyclic voltammetry and absorption spectroscopy are used to investigate the electronic properties of this hybrid electroactive material. The oligomer has a band gap of 2.1 eV, and the material can be oxidized through the sexithiophene and TTF units simultaneously.

Original language	English (US)
Pages (from-to)	1601-1604
Number of pages	4
Journal	Organic letters
Volume	9
Issue number	8
DOIs	https://doi.org/10.1021/ol070366h
State	Published - Apr 12 2007
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "Equation presented We report the synthesis of a novel end-capped sexithiophene derivative bearing two pendent, fused tetrathiafulvalene (TTF) units linked to the main chain through 1,4-dithiin heterocycles. Cyclic voltammetry and absorption spectroscopy are used to investigate the electronic properties of this hybrid electroactive material. The oligomer has a band gap of 2.1 eV, and the material can be oxidized through the sexithiophene and TTF units simultaneously.",

author = "Kanibolotsky, {Alexander L.} and Lyudmila Kanibolotskaya and Sergey Gordeyev and Skabara, {Peter J.} and Iain McCulloch and Rory Berridge and Lohr, {Jan E.} and Filippo Marchioni and Fred Wudl",

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T1 - Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units

AU - Kanibolotsky, Alexander L.

AU - Kanibolotskaya, Lyudmila

AU - Gordeyev, Sergey

AU - Skabara, Peter J.

AU - McCulloch, Iain

AU - Berridge, Rory

AU - Lohr, Jan E.

AU - Marchioni, Filippo

AU - Wudl, Fred

PY - 2007/4/12

Y1 - 2007/4/12

N2 - Equation presented We report the synthesis of a novel end-capped sexithiophene derivative bearing two pendent, fused tetrathiafulvalene (TTF) units linked to the main chain through 1,4-dithiin heterocycles. Cyclic voltammetry and absorption spectroscopy are used to investigate the electronic properties of this hybrid electroactive material. The oligomer has a band gap of 2.1 eV, and the material can be oxidized through the sexithiophene and TTF units simultaneously.

AB - Equation presented We report the synthesis of a novel end-capped sexithiophene derivative bearing two pendent, fused tetrathiafulvalene (TTF) units linked to the main chain through 1,4-dithiin heterocycles. Cyclic voltammetry and absorption spectroscopy are used to investigate the electronic properties of this hybrid electroactive material. The oligomer has a band gap of 2.1 eV, and the material can be oxidized through the sexithiophene and TTF units simultaneously.

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Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units

Abstract

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