Synthesis and characterization of Ba3(Pb1-xBix)2O7

R. J. Cava; H. Takagi; H. W. Zandbergen; B. Hessen; J. J. Krajewski; W. F. Peck

doi:10.1103/PhysRevB.46.14101

Synthesis and characterization of Ba3(Pb1-xBix)2O7

R. J. Cava, H. Takagi, H. W. Zandbergen, B. Hessen, J. J. Krajewski, W. F. Peck

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Abstract

The synthesis and initial characterization of a layered perovskite-based lead-bismuth oxide are reported. The phase, Ba3(Pb1-xBix)2O7, for 0≤x≤0.5, is the n=2 member of the Ruddlesden-Popper series An+1BnO3n+1. It can be synthesized only under very narrowly defined conditions. Despite the analogy to the well-known three-dimensional perovskite superconductor BaPb0.75Bi0.25O3, layered Ba3Pb2O7 does not become superconducting (down to 1.8 K) on doping with Bi.

Original language	English (US)
Pages (from-to)	14101-14104
Number of pages	4
Journal	Physical Review B
Volume	46
Issue number	21
DOIs	https://doi.org/10.1103/PhysRevB.46.14101
State	Published - 1992
Externally published	Yes

All Science Journal Classification (ASJC) codes

Condensed Matter Physics

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10.1103/PhysRevB.46.14101

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title = "Synthesis and characterization of Ba3(Pb1-xBix)2O7",

abstract = "The synthesis and initial characterization of a layered perovskite-based lead-bismuth oxide are reported. The phase, Ba3(Pb1-xBix)2O7, for 0≤x≤0.5, is the n=2 member of the Ruddlesden-Popper series An+1BnO3n+1. It can be synthesized only under very narrowly defined conditions. Despite the analogy to the well-known three-dimensional perovskite superconductor BaPb0.75Bi0.25O3, layered Ba3Pb2O7 does not become superconducting (down to 1.8 K) on doping with Bi.",

author = "Cava, \{R. J.\} and H. Takagi and Zandbergen, \{H. W.\} and B. Hessen and Krajewski, \{J. J.\} and Peck, \{W. F.\}",

year = "1992",

doi = "10.1103/PhysRevB.46.14101",

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journal = "Physical Review B",

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T1 - Synthesis and characterization of Ba3(Pb1-xBix)2O7

AU - Cava, R. J.

AU - Takagi, H.

AU - Zandbergen, H. W.

AU - Hessen, B.

AU - Krajewski, J. J.

AU - Peck, W. F.

PY - 1992

Y1 - 1992

N2 - The synthesis and initial characterization of a layered perovskite-based lead-bismuth oxide are reported. The phase, Ba3(Pb1-xBix)2O7, for 0≤x≤0.5, is the n=2 member of the Ruddlesden-Popper series An+1BnO3n+1. It can be synthesized only under very narrowly defined conditions. Despite the analogy to the well-known three-dimensional perovskite superconductor BaPb0.75Bi0.25O3, layered Ba3Pb2O7 does not become superconducting (down to 1.8 K) on doping with Bi.

AB - The synthesis and initial characterization of a layered perovskite-based lead-bismuth oxide are reported. The phase, Ba3(Pb1-xBix)2O7, for 0≤x≤0.5, is the n=2 member of the Ruddlesden-Popper series An+1BnO3n+1. It can be synthesized only under very narrowly defined conditions. Despite the analogy to the well-known three-dimensional perovskite superconductor BaPb0.75Bi0.25O3, layered Ba3Pb2O7 does not become superconducting (down to 1.8 K) on doping with Bi.

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DO - 10.1103/PhysRevB.46.14101

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VL - 46

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EP - 14104

JO - Physical Review B

JF - Physical Review B

IS - 21

ER -

Synthesis and characterization of Ba3(Pb1-xBix)2O7

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