Synthesis and characterization of an n=6 Aurivillius phase incorporating magnetically active manganese, Bi7 (Mn,Ti)6 O21

M. A. Zurbuchen; R. S. Freitas; M. J. Wilson; P. Schiffer; M. Roeckerath; J. Schubert; M. D. Biegalski; G. H. Mehta; D. J. Comstock; J. H. Lee; Y. Jia; D. G. Schlom

doi:10.1063/1.2756163

Synthesis and characterization of an n=6 Aurivillius phase incorporating magnetically active manganese, Bi7 (Mn,Ti)6 O21

M. A. Zurbuchen
, R. S. Freitas
, M. J. Wilson
, P. Schiffer
, M. Roeckerath
, J. Schubert
, M. D. Biegalski
, G. H. Mehta
, D. J. Comstock
, J. H. Lee
, Y. Jia
, D. G. Schlom

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Epitaxial films of Bi7 Mn3.75 Ti2.25 O21 were prepared to yield a previously unsynthesized material. The superlattice phase is produced by incorporating the magnetoelectric BiMn O3 into the perovskite substructure of the ferroelectric Bi4 Ti3 O12, a strategy which is hoped to yield previously undiscovered multiferroic materials. X-ray diffraction and transmission electron microscopy (TEM) confirm synthesis of an epitaxial n=6 Aurivillius phase. Magnetization measurements show ferromagnetic behavior with a Curie point of 55 K, but electronic polarization measurements show no remanent polarization. Rutherford backscattering spectrometry indicates a channeling minimum min of 22%, consistent with the high density of out-of-phase domain boundaries observed by TEM.

Original language	English (US)
Article number	033113
Journal	Applied Physics Letters
Volume	91
Issue number	3
DOIs	https://doi.org/10.1063/1.2756163
State	Published - 2007

All Science Journal Classification (ASJC) codes

Physics and Astronomy (miscellaneous)

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10.1063/1.2756163

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Zurbuchen, M. A., Freitas, R. S., Wilson, M. J., Schiffer, P., Roeckerath, M., Schubert, J., Biegalski, M. D., Mehta, G. H., Comstock, D. J., Lee, J. H., Jia, Y., & Schlom, D. G. (2007). Synthesis and characterization of an n=6 Aurivillius phase incorporating magnetically active manganese, Bi7 (Mn,Ti)6 O21. Applied Physics Letters, 91(3), Article 033113. https://doi.org/10.1063/1.2756163

@article{93faeb05e0344f468f89d30e6898b9c9,

title = "Synthesis and characterization of an n=6 Aurivillius phase incorporating magnetically active manganese, Bi7 (Mn,Ti)6 O21",

abstract = "Epitaxial films of Bi7 Mn3.75 Ti2.25 O21 were prepared to yield a previously unsynthesized material. The superlattice phase is produced by incorporating the magnetoelectric BiMn O3 into the perovskite substructure of the ferroelectric Bi4 Ti3 O12, a strategy which is hoped to yield previously undiscovered multiferroic materials. X-ray diffraction and transmission electron microscopy (TEM) confirm synthesis of an epitaxial n=6 Aurivillius phase. Magnetization measurements show ferromagnetic behavior with a Curie point of 55 K, but electronic polarization measurements show no remanent polarization. Rutherford backscattering spectrometry indicates a channeling minimum min of 22\%, consistent with the high density of out-of-phase domain boundaries observed by TEM.",

author = "Zurbuchen, \{M. A.\} and Freitas, \{R. S.\} and Wilson, \{M. J.\} and P. Schiffer and M. Roeckerath and J. Schubert and Biegalski, \{M. D.\} and Mehta, \{G. H.\} and Comstock, \{D. J.\} and Lee, \{J. H.\} and Y. Jia and Schlom, \{D. G.\}",

note = "Funding Information: The authors acknowledge support of the U.S. Department of Energy through Grant No. DE-FG02-03ER46063, National Science Foundation through Grant No. DMR-0213623, and National Research Council Research Associateship Postdoctoral Award at the National Institute of Standards and Technology. R.S.F. thanks CNPq-Brazil for sponsorship.",

year = "2007",

doi = "10.1063/1.2756163",

language = "English (US)",

volume = "91",

journal = "Applied Physics Letters",

issn = "0003-6951",

publisher = "American Institute of Physics",

number = "3",

}

TY - JOUR

T1 - Synthesis and characterization of an n=6 Aurivillius phase incorporating magnetically active manganese, Bi7 (Mn,Ti)6 O21

AU - Zurbuchen, M. A.

AU - Freitas, R. S.

AU - Wilson, M. J.

AU - Schiffer, P.

AU - Roeckerath, M.

AU - Schubert, J.

AU - Biegalski, M. D.

AU - Mehta, G. H.

AU - Comstock, D. J.

AU - Lee, J. H.

AU - Jia, Y.

AU - Schlom, D. G.

N1 - Funding Information: The authors acknowledge support of the U.S. Department of Energy through Grant No. DE-FG02-03ER46063, National Science Foundation through Grant No. DMR-0213623, and National Research Council Research Associateship Postdoctoral Award at the National Institute of Standards and Technology. R.S.F. thanks CNPq-Brazil for sponsorship.

PY - 2007

Y1 - 2007

N2 - Epitaxial films of Bi7 Mn3.75 Ti2.25 O21 were prepared to yield a previously unsynthesized material. The superlattice phase is produced by incorporating the magnetoelectric BiMn O3 into the perovskite substructure of the ferroelectric Bi4 Ti3 O12, a strategy which is hoped to yield previously undiscovered multiferroic materials. X-ray diffraction and transmission electron microscopy (TEM) confirm synthesis of an epitaxial n=6 Aurivillius phase. Magnetization measurements show ferromagnetic behavior with a Curie point of 55 K, but electronic polarization measurements show no remanent polarization. Rutherford backscattering spectrometry indicates a channeling minimum min of 22%, consistent with the high density of out-of-phase domain boundaries observed by TEM.

AB - Epitaxial films of Bi7 Mn3.75 Ti2.25 O21 were prepared to yield a previously unsynthesized material. The superlattice phase is produced by incorporating the magnetoelectric BiMn O3 into the perovskite substructure of the ferroelectric Bi4 Ti3 O12, a strategy which is hoped to yield previously undiscovered multiferroic materials. X-ray diffraction and transmission electron microscopy (TEM) confirm synthesis of an epitaxial n=6 Aurivillius phase. Magnetization measurements show ferromagnetic behavior with a Curie point of 55 K, but electronic polarization measurements show no remanent polarization. Rutherford backscattering spectrometry indicates a channeling minimum min of 22%, consistent with the high density of out-of-phase domain boundaries observed by TEM.

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SN - 0003-6951

VL - 91

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 3

M1 - 033113

ER -

Synthesis and characterization of an n=6 Aurivillius phase incorporating magnetically active manganese, Bi7 (Mn,Ti)6 O21

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