Surface micellization patterns of quaternary ammonium surfactants on mica

Heather N. Patrick, Gregory G. Warr, Srinivas Manne, Ilhan A. Aksay

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159 Scopus citations

Abstract

The microscopic equilibrium structures of adsorbed films of quaternary ammonium surfactants on mica have been investigated by noncontact atomic force microscopy imaging as a function of alkyl chain length and headgroup structure. Spherical and cylindrical surface micelles were observed; these were found to be related to bulk solution self-assembly and the surfactant packing parameter, v/aolc. Shape transitions in the surface aggregates were observed on changing the counterion between chloride, bromide, and salicylate.

Original languageEnglish (US)
Pages (from-to)1685-1692
Number of pages8
JournalLangmuir
Volume15
Issue number5
DOIs
StatePublished - Jan 1 1999

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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    Patrick, H. N., Warr, G. G., Manne, S., & Aksay, I. A. (1999). Surface micellization patterns of quaternary ammonium surfactants on mica. Langmuir, 15(5), 1685-1692. https://doi.org/10.1021/la981612o