Substituent Effects for the Oleflnation of Aldehydes by Zirconium “Metalloazines”

Georgia M. Arvanitis, Jeffrey Schwartz

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The reaction between Zr(IV) “metalloazines” and aldehydes affords unsymmetrical olefins and azines. Relative rates for formation of these species (and corresponding yields) were found to depend on the electron-donating ability of the metalloazine and on the electron-accepting ability of the aldehyde. Second-order rate constants were determined, and a reaction mechanism for olefin synthesis is proposed based on observed electronic effects.

Original languageEnglish (US)
Pages (from-to)421-423
Number of pages3
JournalOrganometallics
Volume6
Issue number2
DOIs
StatePublished - Feb 1 1987

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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