TY - JOUR
T1 - SUB-TRIPLE LIQUIDS, THE SUPERCOOLED LIQUID SPINODAL, AND THE NATURE OF TENSILE INSTABILITY.
AU - D'Antonio, Michael C.
AU - Debenedetti, Pablo G.
PY - 1986
Y1 - 1986
N2 - A sub-triple liquid is a metastable liquid whose temperature and pressure are both lower than its triple point values. The sub-triple state cannot be attained either isobarically or isothermally from the stable region without previous penetration into metastable regions. The implications of the existence of spinodal curve for supercooled liquids can be derived from thermodynamic reasoning: the existence of such a limit, however, cannot be proven thermodynamically. This paper will discuss the significance of the Maxwell construction for a supercooled liquid without a spinodal curve, as well as the consequences of the existence of this stability limit.
AB - A sub-triple liquid is a metastable liquid whose temperature and pressure are both lower than its triple point values. The sub-triple state cannot be attained either isobarically or isothermally from the stable region without previous penetration into metastable regions. The implications of the existence of spinodal curve for supercooled liquids can be derived from thermodynamic reasoning: the existence of such a limit, however, cannot be proven thermodynamically. This paper will discuss the significance of the Maxwell construction for a supercooled liquid without a spinodal curve, as well as the consequences of the existence of this stability limit.
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M3 - Conference article
AN - SCOPUS:0022564675
SN - 0402-1215
JO - American Society of Mechanical Engineers (Paper)
JF - American Society of Mechanical Engineers (Paper)
ER -