Structure and dynamics of conjugated polymers in liquid crystalline solvents

P. F. Barbara, W. S. Chang, S. Link, Gregory D. Scholes, Arun Yethiraj

Research output: Chapter in Book/Report/Conference proceedingChapter

30 Scopus citations

Abstract

A combination of single-molecule spectroscopy and analysis with simulations is used to provide detailed information about the structural and dynamic properties of a fluorescent polymer MEH-PPV (poly[2-methoxy-5-(2′- ethylhexyloxy)-1,4-phenylenevinylene]) immersed in a nematic and smectic solvent. In nematic solvents, single-polymer molecules are oriented strongly along the solvent director, much more so than the solvent molecules, confirming Onsager's old prediction. The diffusion anisotropy parallel and perpendicular to the solvent director, however, is less than two, which is similar to that of a spherical colloid in a nematic solvent. In smectic solvents, there is a second orientation of the dissolved polymer perpendicular to the solvent director, which we hypothesize is caused by the polymer occupying the interlayer volume. The research discussed here emphasizes the importance of organization in complex fluids and suggests that the interplay of order on different length scales could be exploited to fabricate novel nanostructured materials.

Original languageEnglish (US)
Title of host publicationAnnual Review of Physical Chemistry
EditorsStephen Leone, Jay Groves, Rustem Ismagilov, Geraldine Richmond
Pages565-584
Number of pages20
DOIs
StatePublished - Jun 12 2007
Externally publishedYes

Publication series

NameAnnual Review of Physical Chemistry
Volume58
ISSN (Print)0066-426X

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

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  • Cite this

    Barbara, P. F., Chang, W. S., Link, S., Scholes, G. D., & Yethiraj, A. (2007). Structure and dynamics of conjugated polymers in liquid crystalline solvents. In S. Leone, J. Groves, R. Ismagilov, & G. Richmond (Eds.), Annual Review of Physical Chemistry (pp. 565-584). (Annual Review of Physical Chemistry; Vol. 58). https://doi.org/10.1146/annurev.physchem.57.032905.104730