Structure and charge control in metal-organic frameworks based on the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane

Mircea Dincǎ; Anne Dailly; Jeffrey R. Long

doi:10.1002/chem.200801336

Structure and charge control in metal-organic frameworks based on the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane

Mircea Dincǎ, Anne Dailly, Jeffrey R. Long

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

Use of the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane enabled isolation of two three-dimensional metal-organic frameworks featuring 4,6- and 4,8-connected nets related to the structures of garnet and fluorite with the formulae Mn₆(ttpm)₃·5DMF·3H₂0 (1) and Cu[(Cu₄Cl)(ttpm)₂]₂·CuCl ₂·5 DMF·11H₂O (2) (H₄ttpm = tetrakis(4-tetrazolylphenyl)methane). The fluorite-type solid 2 displays an unprecedented post-synthetic transformation in which the negative charge of the framework is reduced by extraction of copper(II) chloride. Desolvation of this compound generates Cu₄(ttpm)₂·0.7 CuCl₂ (2d), a microporous material exhibiting a high surface area and significant hydrogen uptake.

Original language	English (US)
Pages (from-to)	10280-10285
Number of pages	6
Journal	Chemistry - A European Journal
Volume	14
Issue number	33
DOIs	https://doi.org/10.1002/chem.200801336
State	Published - Nov 17 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

Keywords

Copper
Manganese
Metal-organic frameworks
Microporous materials
Tetrazoles

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10.1002/chem.200801336

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title = "Structure and charge control in metal-organic frameworks based on the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane",

abstract = "Use of the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane enabled isolation of two three-dimensional metal-organic frameworks featuring 4,6- and 4,8-connected nets related to the structures of garnet and fluorite with the formulae Mn6(ttpm)3·5DMF·3H20 (1) and Cu[(Cu4Cl)(ttpm)2]2·CuCl 2·5 DMF·11H2O (2) (H4ttpm = tetrakis(4-tetrazolylphenyl)methane). The fluorite-type solid 2 displays an unprecedented post-synthetic transformation in which the negative charge of the framework is reduced by extraction of copper(II) chloride. Desolvation of this compound generates Cu4(ttpm)2·0.7 CuCl2 (2d), a microporous material exhibiting a high surface area and significant hydrogen uptake.",

keywords = "Copper, Manganese, Metal-organic frameworks, Microporous materials, Tetrazoles",

author = "Mircea Dincǎ and Anne Dailly and Long, {Jeffrey R.}",

year = "2008",

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doi = "10.1002/chem.200801336",

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volume = "14",

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journal = "Chemistry - A European Journal",

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T1 - Structure and charge control in metal-organic frameworks based on the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane

AU - Dincǎ, Mircea

AU - Dailly, Anne

AU - Long, Jeffrey R.

PY - 2008/11/17

Y1 - 2008/11/17

N2 - Use of the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane enabled isolation of two three-dimensional metal-organic frameworks featuring 4,6- and 4,8-connected nets related to the structures of garnet and fluorite with the formulae Mn6(ttpm)3·5DMF·3H20 (1) and Cu[(Cu4Cl)(ttpm)2]2·CuCl 2·5 DMF·11H2O (2) (H4ttpm = tetrakis(4-tetrazolylphenyl)methane). The fluorite-type solid 2 displays an unprecedented post-synthetic transformation in which the negative charge of the framework is reduced by extraction of copper(II) chloride. Desolvation of this compound generates Cu4(ttpm)2·0.7 CuCl2 (2d), a microporous material exhibiting a high surface area and significant hydrogen uptake.

AB - Use of the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane enabled isolation of two three-dimensional metal-organic frameworks featuring 4,6- and 4,8-connected nets related to the structures of garnet and fluorite with the formulae Mn6(ttpm)3·5DMF·3H20 (1) and Cu[(Cu4Cl)(ttpm)2]2·CuCl 2·5 DMF·11H2O (2) (H4ttpm = tetrakis(4-tetrazolylphenyl)methane). The fluorite-type solid 2 displays an unprecedented post-synthetic transformation in which the negative charge of the framework is reduced by extraction of copper(II) chloride. Desolvation of this compound generates Cu4(ttpm)2·0.7 CuCl2 (2d), a microporous material exhibiting a high surface area and significant hydrogen uptake.

KW - Copper

KW - Manganese

KW - Metal-organic frameworks

KW - Microporous materials

KW - Tetrazoles

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JO - Chemistry - A European Journal

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ER -

Structure and charge control in metal-organic frameworks based on the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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