Structural aspects of lithium insertion in oxides: LixReO3 and Li2FeV3O8

R. J. Cava; A. Santoro; D. W. Murphy; S. Zahurak; R. S. Roth

doi:10.1016/0167-2738(81)90258-7

Structural aspects of lithium insertion in oxides: Li_xReO₃ and Li₂FeV₃O₈

R. J. Cava, A. Santoro, D. W. Murphy, S. Zahurak, R. S. Roth

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

We have determined the crystal structures of LiReO₃, Li₂ReO₃ and Li₂FeV₃O₈, obtained by Li insertion of ReO₃ and FeV₃O₈, by neutron diffraction powder profile analysis. The ReO₃ host lattice is exclusively corner shared and undergoes significant twisting on Li insertion. The FeV₃O₈ host lattice is extensively edge shared and changes little on Li insertion. The Li is accommodated in 6 coordinate sites in the rhenates and 5 coordinate sites in the iron vanadate.

Original language	English (US)
Pages (from-to)	323-326
Number of pages	4
Journal	Solid State Ionics
Volume	5
Issue number	C
DOIs	https://doi.org/10.1016/0167-2738(81)90258-7
State	Published - Oct 1981
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Structural aspects of lithium insertion in oxides: LixReO3 and Li2FeV3O8",

abstract = "We have determined the crystal structures of LiReO3, Li2ReO3 and Li2FeV3O8, obtained by Li insertion of ReO3 and FeV3O8, by neutron diffraction powder profile analysis. The ReO3 host lattice is exclusively corner shared and undergoes significant twisting on Li insertion. The FeV3O8 host lattice is extensively edge shared and changes little on Li insertion. The Li is accommodated in 6 coordinate sites in the rhenates and 5 coordinate sites in the iron vanadate.",

author = "Cava, {R. J.} and A. Santoro and Murphy, {D. W.} and S. Zahurak and Roth, {R. S.}",

year = "1981",

month = oct,

doi = "10.1016/0167-2738(81)90258-7",

language = "English (US)",

volume = "5",

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T1 - Structural aspects of lithium insertion in oxides

T2 - LixReO3 and Li2FeV3O8

AU - Cava, R. J.

AU - Santoro, A.

AU - Murphy, D. W.

AU - Zahurak, S.

AU - Roth, R. S.

PY - 1981/10

Y1 - 1981/10

N2 - We have determined the crystal structures of LiReO3, Li2ReO3 and Li2FeV3O8, obtained by Li insertion of ReO3 and FeV3O8, by neutron diffraction powder profile analysis. The ReO3 host lattice is exclusively corner shared and undergoes significant twisting on Li insertion. The FeV3O8 host lattice is extensively edge shared and changes little on Li insertion. The Li is accommodated in 6 coordinate sites in the rhenates and 5 coordinate sites in the iron vanadate.

AB - We have determined the crystal structures of LiReO3, Li2ReO3 and Li2FeV3O8, obtained by Li insertion of ReO3 and FeV3O8, by neutron diffraction powder profile analysis. The ReO3 host lattice is exclusively corner shared and undergoes significant twisting on Li insertion. The FeV3O8 host lattice is extensively edge shared and changes little on Li insertion. The Li is accommodated in 6 coordinate sites in the rhenates and 5 coordinate sites in the iron vanadate.

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JF - Solid State Ionics

IS - C

ER -

Structural aspects of lithium insertion in oxides: Li_xReO₃ and Li₂FeV₃O₈

Abstract

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