Structural anomalies at the disappearance of superconductivity in Ba2YCu3O7-δ: Evidence for charge transfer from chains to planes

R. J. Cava; B. Batlogg; K. M. Rabe; E. A. Rietman; P. K. Gallagher; L. W. Rupp

doi:10.1016/0921-4534(88)90015-9

Structural anomalies at the disappearance of superconductivity in Ba₂YCu₃O_7-δ: Evidence for charge transfer from chains to planes

R. J. Cava
, B. Batlogg
, K. M. Rabe
, E. A. Rietman
, P. K. Gallagher
, L. W. Rupp

Research output: Contribution to journal › Article › peer-review

253 Scopus citations

Abstract

In systematic studies of oxygen-deficient Ba₂YCu₃O_7-δ, we have found that a structural anomaly occurs at the composition where bulk superconductivity disappears. The observed step-like increase in the c lattice parameter, when associated with changes in the atomic positions within the unit cell, indicates that superconductivity is lost due to a charge redistribution from the copper-oxygen chains to the copper-oxygen planes. This is microscopic experimental evidence establishing the role of secondary structural elements in the layered copper-oxide high-T_c superconductors.

Original language	English (US)
Pages (from-to)	523-527
Number of pages	5
Journal	Physica C: Superconductivity and its Applications
Volume	156
Issue number	4
DOIs	https://doi.org/10.1016/0921-4534(88)90015-9
State	Published - Nov 1 1988
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Energy Engineering and Power Technology
Electrical and Electronic Engineering

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10.1016/0921-4534(88)90015-9

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title = "Structural anomalies at the disappearance of superconductivity in Ba2YCu3O7-δ: Evidence for charge transfer from chains to planes",

abstract = "In systematic studies of oxygen-deficient Ba2YCu3O7-δ, we have found that a structural anomaly occurs at the composition where bulk superconductivity disappears. The observed step-like increase in the c lattice parameter, when associated with changes in the atomic positions within the unit cell, indicates that superconductivity is lost due to a charge redistribution from the copper-oxygen chains to the copper-oxygen planes. This is microscopic experimental evidence establishing the role of secondary structural elements in the layered copper-oxide high-Tc superconductors.",

author = "Cava, \{R. J.\} and B. Batlogg and Rabe, \{K. M.\} and Rietman, \{E. A.\} and Gallagher, \{P. K.\} and Rupp, \{L. W.\}",

year = "1988",

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doi = "10.1016/0921-4534(88)90015-9",

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T1 - Structural anomalies at the disappearance of superconductivity in Ba2YCu3O7-δ

T2 - Evidence for charge transfer from chains to planes

AU - Cava, R. J.

AU - Batlogg, B.

AU - Rabe, K. M.

AU - Rietman, E. A.

AU - Gallagher, P. K.

AU - Rupp, L. W.

PY - 1988/11/1

Y1 - 1988/11/1

N2 - In systematic studies of oxygen-deficient Ba2YCu3O7-δ, we have found that a structural anomaly occurs at the composition where bulk superconductivity disappears. The observed step-like increase in the c lattice parameter, when associated with changes in the atomic positions within the unit cell, indicates that superconductivity is lost due to a charge redistribution from the copper-oxygen chains to the copper-oxygen planes. This is microscopic experimental evidence establishing the role of secondary structural elements in the layered copper-oxide high-Tc superconductors.

AB - In systematic studies of oxygen-deficient Ba2YCu3O7-δ, we have found that a structural anomaly occurs at the composition where bulk superconductivity disappears. The observed step-like increase in the c lattice parameter, when associated with changes in the atomic positions within the unit cell, indicates that superconductivity is lost due to a charge redistribution from the copper-oxygen chains to the copper-oxygen planes. This is microscopic experimental evidence establishing the role of secondary structural elements in the layered copper-oxide high-Tc superconductors.

UR - https://www.scopus.com/pages/publications/0024108317

UR - https://www.scopus.com/pages/publications/0024108317#tab=citedBy

U2 - 10.1016/0921-4534(88)90015-9

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VL - 156

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JO - Physica C: Superconductivity and its Applications

JF - Physica C: Superconductivity and its Applications

IS - 4

ER -

Structural anomalies at the disappearance of superconductivity in Ba₂YCu₃O_7-δ: Evidence for charge transfer from chains to planes

Abstract

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