Steric effects and competitive intra-and intermolecular host-guest complexation between beta-cyclodextrin and adamantyl substituted poly(acrylate)s in water: A 1H NMR, rheological and preparative study

Xuhong Guo; Jie Wang; Li Li; Duc Truc Pham; Philip Clements; Stephen F. Lincoln; Bruce L. May; Qingchuan Chen; Li Zheng; Robert K. Prud'homme

doi:10.1002/polb.22052

Steric effects and competitive intra-and intermolecular host-guest complexation between beta-cyclodextrin and adamantyl substituted poly(acrylate)s in water: A ¹H NMR, rheological and preparative study

Xuhong Guo, Jie Wang, Li Li, Duc Truc Pham, Philip Clements, Stephen F. Lincoln, Bruce L. May, Qingchuan Chen, Li Zheng, Robert K. Prud'homme

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A ¹H NMR and rheological study of host-guest complexation interactions between three β-cyclodextrin and three adamantyl substituted poly(acrylate)s, and also between them and adamantan-1-carboxylate and native β-cyclodextrin, respectively, is reported. A close correllation between molecular level interactions and macroscopic characteristics of polymer networks in aqueous solution exists. It is found that intraand intermolecular host-guest complexation between the host β-cyclodextrin and guest adamantyl substituents and the length of the aliphatic tether between them and the poly(acrylate) backbone have important roles. Dominantly, steric effects and competitive intra-and intermolecular host-guest complexation are found to control poly(acrylate) isomeric interstrand linkage in polymer network formation. The preparations of five new 3% randomly substituted poly(acrylate)s are reported.

Original language	English (US)
Pages (from-to)	1818-1825
Number of pages	8
Journal	Journal of Polymer Science, Part B: Polymer Physics
Volume	48
Issue number	16
DOIs	https://doi.org/10.1002/polb.22052
State	Published - Aug 15 2010

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Physical and Theoretical Chemistry
Polymers and Plastics
Materials Chemistry

Keywords

Host-guest complexation
NMR
Poly(acrylate)
Rheology
β-cyclodextrin

Access to Document

10.1002/polb.22052

Cite this

Guo, X., Wang, J., Li, L., Pham, D. T., Clements, P., Lincoln, S. F., May, B. L., Chen, Q., Zheng, L., & Prud'homme, R. K. (2010). Steric effects and competitive intra-and intermolecular host-guest complexation between beta-cyclodextrin and adamantyl substituted poly(acrylate)s in water: A ¹H NMR, rheological and preparative study. Journal of Polymer Science, Part B: Polymer Physics, 48(16), 1818-1825. https://doi.org/10.1002/polb.22052

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title = "Steric effects and competitive intra-and intermolecular host-guest complexation between beta-cyclodextrin and adamantyl substituted poly(acrylate)s in water: A 1H NMR, rheological and preparative study",

abstract = "A 1H NMR and rheological study of host-guest complexation interactions between three β-cyclodextrin and three adamantyl substituted poly(acrylate)s, and also between them and adamantan-1-carboxylate and native β-cyclodextrin, respectively, is reported. A close correllation between molecular level interactions and macroscopic characteristics of polymer networks in aqueous solution exists. It is found that intraand intermolecular host-guest complexation between the host β-cyclodextrin and guest adamantyl substituents and the length of the aliphatic tether between them and the poly(acrylate) backbone have important roles. Dominantly, steric effects and competitive intra-and intermolecular host-guest complexation are found to control poly(acrylate) isomeric interstrand linkage in polymer network formation. The preparations of five new 3% randomly substituted poly(acrylate)s are reported.",

keywords = "Host-guest complexation, NMR, Poly(acrylate), Rheology, β-cyclodextrin",

author = "Xuhong Guo and Jie Wang and Li Li and Pham, {Duc Truc} and Philip Clements and Lincoln, {Stephen F.} and May, {Bruce L.} and Qingchuan Chen and Li Zheng and Prud'homme, {Robert K.}",

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Guo, X, Wang, J, Li, L, Pham, DT, Clements, P, Lincoln, SF, May, BL, Chen, Q, Zheng, L & Prud'homme, RK 2010, 'Steric effects and competitive intra-and intermolecular host-guest complexation between beta-cyclodextrin and adamantyl substituted poly(acrylate)s in water: A ¹H NMR, rheological and preparative study', Journal of Polymer Science, Part B: Polymer Physics, vol. 48, no. 16, pp. 1818-1825. https://doi.org/10.1002/polb.22052

Steric effects and competitive intra-and intermolecular host-guest complexation between beta-cyclodextrin and adamantyl substituted poly(acrylate)s in water: A ¹H NMR, rheological and preparative study. / Guo, Xuhong; Wang, Jie; Li, Li et al.
In: Journal of Polymer Science, Part B: Polymer Physics, Vol. 48, No. 16, 15.08.2010, p. 1818-1825.

Research output: Contribution to journal › Article › peer-review

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AU - Wang, Jie

AU - Li, Li

AU - Pham, Duc Truc

AU - Clements, Philip

AU - Lincoln, Stephen F.

AU - May, Bruce L.

AU - Chen, Qingchuan

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AU - Prud'homme, Robert K.

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AB - A 1H NMR and rheological study of host-guest complexation interactions between three β-cyclodextrin and three adamantyl substituted poly(acrylate)s, and also between them and adamantan-1-carboxylate and native β-cyclodextrin, respectively, is reported. A close correllation between molecular level interactions and macroscopic characteristics of polymer networks in aqueous solution exists. It is found that intraand intermolecular host-guest complexation between the host β-cyclodextrin and guest adamantyl substituents and the length of the aliphatic tether between them and the poly(acrylate) backbone have important roles. Dominantly, steric effects and competitive intra-and intermolecular host-guest complexation are found to control poly(acrylate) isomeric interstrand linkage in polymer network formation. The preparations of five new 3% randomly substituted poly(acrylate)s are reported.

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