Stereochemistry of the Primary Carbon. XVII. Absolute Configuration of 1-ButanoI-1-d

A. Streitwieser, I. Schwager, L. Verbit, H. Rabitz

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

(+)-1-Butanol-1-d was converted by reactions of known stereochemistry to (R)-(-)-1-bromopentane-2-d which was also related to (S)-(-)-pentane-2-d via asymmetric hydroboration reactions on 1-pentene-2-d. The configurations previously assigned to the deuterio alcohols on the basis of mechanisms are confirmed by these interconversions.

Original languageEnglish (US)
Pages (from-to)1532-1534
Number of pages3
JournalJournal of Organic Chemistry
Volume32
Issue number5
DOIs
StatePublished - Jan 1 1967
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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