Stable dye-sensitized solar cell electrolytes based on cobalt(ii)/(iii) complexes of a hexadentate pyridyl ligand

Muhammad K. Kashif; Michael Nippe; Noel W. Duffy; Craig M. Forsyth; Christopher J. Chang; Jeffrey R. Long; Leone Spiccia; Udo Bach

doi:10.1002/anie.201300070

Stable dye-sensitized solar cell electrolytes based on cobalt(ii)/(iii) complexes of a hexadentate pyridyl ligand

Muhammad K. Kashif
, Michael Nippe
, Noel W. Duffy
, Craig M. Forsyth
, Christopher J. Chang
, Jeffrey R. Long
, Leone Spiccia
, Udo Bach

Research output: Contribution to journal › Article › peer-review

92 Scopus citations

Abstract

Energy conversion: A cobalt redox mediator, [Co(bpyPY4)]^2+/3+, based on a hexadentate polypyridyl ligand, was developed. Dye-sensitized solar cells (DSCs) made with this redox mediator showed improved stability and slightly higher efficiencies compared to [Co(bpy)₃] ^2+/3+-based devices. Long-term stability evaluation of DSCs based on [Co(bpyPY4)]^2+/3+ revealed excellent stability under full irradiation conditions (see picture).

Original language	English (US)
Pages (from-to)	5527-5531
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	21
DOIs	https://doi.org/10.1002/anie.201300070
State	Published - May 17 2013
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

cobalt electrolytes
dye-sensitized solar cells
energy conversion
ligand engineering

Access to Document

10.1002/anie.201300070

Cite this

@article{d3327bb3d0bf43e08d39a001e36c1637,

title = "Stable dye-sensitized solar cell electrolytes based on cobalt(ii)/(iii) complexes of a hexadentate pyridyl ligand",

abstract = "Energy conversion: A cobalt redox mediator, [Co(bpyPY4)]2+/3+, based on a hexadentate polypyridyl ligand, was developed. Dye-sensitized solar cells (DSCs) made with this redox mediator showed improved stability and slightly higher efficiencies compared to [Co(bpy)3] 2+/3+-based devices. Long-term stability evaluation of DSCs based on [Co(bpyPY4)]2+/3+ revealed excellent stability under full irradiation conditions (see picture).",

keywords = "cobalt electrolytes, dye-sensitized solar cells, energy conversion, ligand engineering",

author = "Kashif, \{Muhammad K.\} and Michael Nippe and Duffy, \{Noel W.\} and Forsyth, \{Craig M.\} and Chang, \{Christopher J.\} and Long, \{Jeffrey R.\} and Leone Spiccia and Udo Bach",

year = "2013",

month = may,

day = "17",

doi = "10.1002/anie.201300070",

language = "English (US)",

volume = "52",

pages = "5527--5531",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "21",

}

TY - JOUR

T1 - Stable dye-sensitized solar cell electrolytes based on cobalt(ii)/(iii) complexes of a hexadentate pyridyl ligand

AU - Kashif, Muhammad K.

AU - Nippe, Michael

AU - Duffy, Noel W.

AU - Forsyth, Craig M.

AU - Chang, Christopher J.

AU - Long, Jeffrey R.

AU - Spiccia, Leone

AU - Bach, Udo

PY - 2013/5/17

Y1 - 2013/5/17

N2 - Energy conversion: A cobalt redox mediator, [Co(bpyPY4)]2+/3+, based on a hexadentate polypyridyl ligand, was developed. Dye-sensitized solar cells (DSCs) made with this redox mediator showed improved stability and slightly higher efficiencies compared to [Co(bpy)3] 2+/3+-based devices. Long-term stability evaluation of DSCs based on [Co(bpyPY4)]2+/3+ revealed excellent stability under full irradiation conditions (see picture).

AB - Energy conversion: A cobalt redox mediator, [Co(bpyPY4)]2+/3+, based on a hexadentate polypyridyl ligand, was developed. Dye-sensitized solar cells (DSCs) made with this redox mediator showed improved stability and slightly higher efficiencies compared to [Co(bpy)3] 2+/3+-based devices. Long-term stability evaluation of DSCs based on [Co(bpyPY4)]2+/3+ revealed excellent stability under full irradiation conditions (see picture).

KW - cobalt electrolytes

KW - dye-sensitized solar cells

KW - energy conversion

KW - ligand engineering

UR - https://www.scopus.com/pages/publications/84877715119

UR - https://www.scopus.com/pages/publications/84877715119#tab=citedBy

U2 - 10.1002/anie.201300070

DO - 10.1002/anie.201300070

M3 - Article

C2 - 23606377

AN - SCOPUS:84877715119

SN - 1433-7851

VL - 52

SP - 5527

EP - 5531

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 21

ER -

Stable dye-sensitized solar cell electrolytes based on cobalt(ii)/(iii) complexes of a hexadentate pyridyl ligand

Abstract

All Science Journal Classification (ASJC) codes

Keywords

Access to Document

Other files and links

Fingerprint

Cite this