Stabilization of self-assembled monolayers of carboxylic acids on native oxides of metals

Yael G. Aronoff; Bo Chen; Gang Lu; Carwai Seto; Jeffrey Schwartz; Steven L. Bernasek

doi:10.1021/ja953848+

Stabilization of self-assembled monolayers of carboxylic acids on native oxides of metals

Yael G. Aronoff, Bo Chen, Gang Lu, Carwai Seto, Jeffrey Schwartz, Steven L. Bernasek

Research output: Contribution to journal › Article › peer-review

95 Scopus citations

Abstract

Alkanoic acids adsorb weakly to the native oxide surface of aluminum. Treating the oxide surface first with an alkoxide of zirconium provides for strong subsequent adsorption of the alkanoic acid. The formation of an interfacial zirconium carboxylate gives rise to this strong adhesion. A combination of quartz crystal microbalance and ultrahigh-vacuum IR spectroscopic techniques were used to establish the stoichiometry and structural features of the interfacial zirconium carboxylate film.

Original language	English (US)
Pages (from-to)	259-262
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	119
Issue number	2
DOIs	https://doi.org/10.1021/ja953848+
State	Published - Jan 15 1997

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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abstract = "Alkanoic acids adsorb weakly to the native oxide surface of aluminum. Treating the oxide surface first with an alkoxide of zirconium provides for strong subsequent adsorption of the alkanoic acid. The formation of an interfacial zirconium carboxylate gives rise to this strong adhesion. A combination of quartz crystal microbalance and ultrahigh-vacuum IR spectroscopic techniques were used to establish the stoichiometry and structural features of the interfacial zirconium carboxylate film.",

author = "Aronoff, {Yael G.} and Bo Chen and Gang Lu and Carwai Seto and Jeffrey Schwartz and Bernasek, {Steven L.}",

year = "1997",

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T1 - Stabilization of self-assembled monolayers of carboxylic acids on native oxides of metals

AU - Aronoff, Yael G.

AU - Chen, Bo

AU - Lu, Gang

AU - Seto, Carwai

AU - Schwartz, Jeffrey

AU - Bernasek, Steven L.

PY - 1997/1/15

Y1 - 1997/1/15

N2 - Alkanoic acids adsorb weakly to the native oxide surface of aluminum. Treating the oxide surface first with an alkoxide of zirconium provides for strong subsequent adsorption of the alkanoic acid. The formation of an interfacial zirconium carboxylate gives rise to this strong adhesion. A combination of quartz crystal microbalance and ultrahigh-vacuum IR spectroscopic techniques were used to establish the stoichiometry and structural features of the interfacial zirconium carboxylate film.

AB - Alkanoic acids adsorb weakly to the native oxide surface of aluminum. Treating the oxide surface first with an alkoxide of zirconium provides for strong subsequent adsorption of the alkanoic acid. The formation of an interfacial zirconium carboxylate gives rise to this strong adhesion. A combination of quartz crystal microbalance and ultrahigh-vacuum IR spectroscopic techniques were used to establish the stoichiometry and structural features of the interfacial zirconium carboxylate film.

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U2 - 10.1021/ja953848+

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JF - Journal of the American Chemical Society

IS - 2

ER -

Stabilization of self-assembled monolayers of carboxylic acids on native oxides of metals

Abstract

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