Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants

Camille Boucher-Jacobs; Bo Li; Charles M. Schroeder; Damien Guironnet

doi:10.1039/c9py00154a

Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants

Camille Boucher-Jacobs
, Bo Li
, Charles M. Schroeder
, Damien Guironnet

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Water-soluble phosphinosulfonate palladium complexes were synthesized by coordination of a surfactant to the metal center. The ethylene polymerization activity of the corresponding catalyst was probed. The surfactant and pH of the solution are shown to influence the activity. A phosphated surfactant resulted in polymerization with the highest activity and stability.

Original language	English (US)
Pages (from-to)	1988-1992
Number of pages	5
Journal	Polymer Chemistry
Volume	10
Issue number	16
DOIs	https://doi.org/10.1039/c9py00154a
State	Published - Apr 28 2019
Externally published	Yes

All Science Journal Classification (ASJC) codes

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

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10.1039/c9py00154a

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title = "Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants",

abstract = "Water-soluble phosphinosulfonate palladium complexes were synthesized by coordination of a surfactant to the metal center. The ethylene polymerization activity of the corresponding catalyst was probed. The surfactant and pH of the solution are shown to influence the activity. A phosphated surfactant resulted in polymerization with the highest activity and stability.",

author = "Camille Boucher-Jacobs and Bo Li and Schroeder, \{Charles M.\} and Damien Guironnet",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

month = apr,

day = "28",

doi = "10.1039/c9py00154a",

language = "English (US)",

volume = "10",

pages = "1988--1992",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants

AU - Boucher-Jacobs, Camille

AU - Li, Bo

AU - Schroeder, Charles M.

AU - Guironnet, Damien

PY - 2019/4/28

Y1 - 2019/4/28

N2 - Water-soluble phosphinosulfonate palladium complexes were synthesized by coordination of a surfactant to the metal center. The ethylene polymerization activity of the corresponding catalyst was probed. The surfactant and pH of the solution are shown to influence the activity. A phosphated surfactant resulted in polymerization with the highest activity and stability.

AB - Water-soluble phosphinosulfonate palladium complexes were synthesized by coordination of a surfactant to the metal center. The ethylene polymerization activity of the corresponding catalyst was probed. The surfactant and pH of the solution are shown to influence the activity. A phosphated surfactant resulted in polymerization with the highest activity and stability.

UR - https://www.scopus.com/pages/publications/85064503531

UR - https://www.scopus.com/pages/publications/85064503531#tab=citedBy

U2 - 10.1039/c9py00154a

DO - 10.1039/c9py00154a

M3 - Article

AN - SCOPUS:85064503531

SN - 1759-9954

VL - 10

SP - 1988

EP - 1992

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 16

ER -

Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants

Abstract

All Science Journal Classification (ASJC) codes

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