TY - JOUR
T1 - SOLID ELECTROLYTE POTENTIOMETRY STUDY OF BUTENE OXIDATION OVER VANADIUM PHOSPHATE CATALYST.
AU - Breckner, E. M.
AU - Sundaresan, Sankaran
AU - Benziger, Jay Burton
PY - 1985/12/1
Y1 - 1985/12/1
N2 - A system which includes a solid state electrochemical cell has been used to study the complex behavior of a vanadium phosphate (VPO) catalyst during butene oxidation. Under reaction conditions of high temperature (750 K) and near-atmosphere pressure, the open circuit voltage of the cell is indicative of the oxygen activity in the catalyst. It was found that as the relative degree of reduction of the catalyst increased, the selectivity to partial oxidation products also increased, while catalytic activity decreased.
AB - A system which includes a solid state electrochemical cell has been used to study the complex behavior of a vanadium phosphate (VPO) catalyst during butene oxidation. Under reaction conditions of high temperature (750 K) and near-atmosphere pressure, the open circuit voltage of the cell is indicative of the oxygen activity in the catalyst. It was found that as the relative degree of reduction of the catalyst increased, the selectivity to partial oxidation products also increased, while catalytic activity decreased.
UR - http://www.scopus.com/inward/record.url?scp=0022245507&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0022245507&partnerID=8YFLogxK
M3 - Conference article
AN - SCOPUS:0022245507
SN - 0196-7282
JO - Annual Meeting - American Institute of Chemical Engineers
JF - Annual Meeting - American Institute of Chemical Engineers
ER -