Soft Chemical Synthesis of HxCrS2: An Antiferromagnetic Material with Alternating Amorphous and Crystalline Layers

Xiaoyu Song; Guangming Cheng; Daniel Weber; Florian Pielnhofer; Shiming Lei; Sebastian Klemenz; Yao Wen Yeh; Kai A. Filsinger; Craig B. Arnold; Nan Yao; Leslie M. Schoop

doi:10.1021/jacs.9b07503

Soft Chemical Synthesis of H_xCrS₂: An Antiferromagnetic Material with Alternating Amorphous and Crystalline Layers

Xiaoyu Song, Guangming Cheng, Daniel Weber, Florian Pielnhofer, Shiming Lei, Sebastian Klemenz, Yao Wen Yeh, Kai A. Filsinger, Craig B. Arnold, Nan Yao, Leslie M. Schoop

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

We report a new H_xCrS₂-based crystalline/amorphous layered material synthesized by soft chemical methods. We study the structural nature and composition of this material with atomic resolution scanning transmission electron microscopy (STEM), revealing a complex structure consisting of alternating layers of amorphous and crystalline lamellae. Furthermore, the magnetic properties show evidence for increased magnetic frustration compared to the parent compound NaCrS₂. Finally, we show that this material can be exfoliated, thus providing a facile synthesis method for chromium-sulfide-based ultrathin layers. The material reported herein can not only be a source of new thin TMD-related sheets for potential application in catalysis but also be of interest for realizing new 2D magnetic materials.

Original language	English (US)
Pages (from-to)	15634-15640
Number of pages	7
Journal	Journal of the American Chemical Society
Volume	141
Issue number	39
DOIs	https://doi.org/10.1021/jacs.9b07503
State	Published - Oct 2 2019

All Science Journal Classification (ASJC) codes

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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title = "Soft Chemical Synthesis of HxCrS2: An Antiferromagnetic Material with Alternating Amorphous and Crystalline Layers",

abstract = "We report a new HxCrS2-based crystalline/amorphous layered material synthesized by soft chemical methods. We study the structural nature and composition of this material with atomic resolution scanning transmission electron microscopy (STEM), revealing a complex structure consisting of alternating layers of amorphous and crystalline lamellae. Furthermore, the magnetic properties show evidence for increased magnetic frustration compared to the parent compound NaCrS2. Finally, we show that this material can be exfoliated, thus providing a facile synthesis method for chromium-sulfide-based ultrathin layers. The material reported herein can not only be a source of new thin TMD-related sheets for potential application in catalysis but also be of interest for realizing new 2D magnetic materials.",

author = "Xiaoyu Song and Guangming Cheng and Daniel Weber and Florian Pielnhofer and Shiming Lei and Sebastian Klemenz and Yeh, {Yao Wen} and Filsinger, {Kai A.} and Arnold, {Craig B.} and Nan Yao and Schoop, {Leslie M.}",

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T2 - An Antiferromagnetic Material with Alternating Amorphous and Crystalline Layers

AU - Song, Xiaoyu

AU - Cheng, Guangming

AU - Weber, Daniel

AU - Pielnhofer, Florian

AU - Lei, Shiming

AU - Klemenz, Sebastian

AU - Yeh, Yao Wen

AU - Filsinger, Kai A.

AU - Arnold, Craig B.

AU - Yao, Nan

AU - Schoop, Leslie M.

PY - 2019/10/2

Y1 - 2019/10/2

N2 - We report a new HxCrS2-based crystalline/amorphous layered material synthesized by soft chemical methods. We study the structural nature and composition of this material with atomic resolution scanning transmission electron microscopy (STEM), revealing a complex structure consisting of alternating layers of amorphous and crystalline lamellae. Furthermore, the magnetic properties show evidence for increased magnetic frustration compared to the parent compound NaCrS2. Finally, we show that this material can be exfoliated, thus providing a facile synthesis method for chromium-sulfide-based ultrathin layers. The material reported herein can not only be a source of new thin TMD-related sheets for potential application in catalysis but also be of interest for realizing new 2D magnetic materials.

AB - We report a new HxCrS2-based crystalline/amorphous layered material synthesized by soft chemical methods. We study the structural nature and composition of this material with atomic resolution scanning transmission electron microscopy (STEM), revealing a complex structure consisting of alternating layers of amorphous and crystalline lamellae. Furthermore, the magnetic properties show evidence for increased magnetic frustration compared to the parent compound NaCrS2. Finally, we show that this material can be exfoliated, thus providing a facile synthesis method for chromium-sulfide-based ultrathin layers. The material reported herein can not only be a source of new thin TMD-related sheets for potential application in catalysis but also be of interest for realizing new 2D magnetic materials.

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Soft Chemical Synthesis of H_xCrS₂: An Antiferromagnetic Material with Alternating Amorphous and Crystalline Layers

Abstract

All Science Journal Classification (ASJC) codes

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