Slow Photoelectron Velocity-Map Imaging Spectroscopy of the ortho-Hydroxyphenoxide Anion

Marissa L. Weichman, Jongjin B. Kim, Daniel M. Neumark

Research output: Contribution to journalArticle

12 Scopus citations

Abstract

We report high-resolution photodetachment spectra of cryogenically cooled ortho-hydroxyphenoxide anions (o-HOC6H4O-) using slow photoelectron velocity-map imaging spectroscopy (cryo-SEVI). We observe transitions to the three lowest-lying electronic states of the ortho-hydroxyphenoxy radical, and resolve detailed vibrational features. Comparison to Franck-Condon simulations allows for clear assignment of vibronic structure. We find an electron affinity of 2.3292(4) eV for the neutral X˜2A′ ground state, improving upon the accuracy of previous experiments. We measure term energies of 1.4574(7) eV and 1.5922(48) eV for the Ã2A′ and B˜2A′ excited states respectively, representing their first resolution and clear assignment. Photodetachment threshold effects are considered to explain the structure of these bands. (Figure Presented).

Original languageEnglish (US)
Pages (from-to)6140-6147
Number of pages8
JournalJournal of Physical Chemistry A
Volume119
Issue number23
DOIs
StatePublished - Jun 11 2015
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

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