Simultaneous detection of atmospheric nitrous oxide and carbon monoxide using a quantum cascade laser

Amir Khan, Kang Sun, David J. Miller, Mark Andrew Zondlo

Research output: Chapter in Book/Report/Conference proceedingConference contribution

8 Scopus citations

Abstract

We describe a non-intrusive, open-path, fast-response compact sensor for simultaneous measurements of nitrous-oxide (N2O) and carbon-monoxide (CO) primarily designed for UAV applications. N2O is the third most important anthropogenic greenhouse gas, but the spatial and temporal distributions of N2O emissions are poorly quantified. On the other hand, CO is an important tracer to distinguish between fossil fuel and biogenic sources. We use a 4.5 micron thermoelectrically-cooled, distributed feedback, continuous wave quantum cascade laser as a mid-infrared radiation source to scan CO and N2O transitions centered at 4538.9 nm and 4539.8 nm respectively. Detection was achieved by a thermo-electrically (TE) cooled 5 micron Indium-Phosphide (InSb) infrared detector. For the first time in this application, a compact cylindrical cell with a pattern configuration to minimize the sensor size with a pathlength of 10 meters (2.54 cm radius mirrors, 25 cm basepath). Wavelength modulation spectroscopy was employed to achieve high sensitivity detection. The detection limit of 10-5 fractional absorbance was achieved at a 10 sec. averaging time. This is equivalent to less than 1 ppbv of N2O and 2 ppbv of CO out of 320 ppbv and 200 ppbv ambient levels respectively. In summary we report a cryogen-free, consumable-free sensor that can operate with 10s W of electrical power and packaged in a small shoe-box size which is ideal for UAV or airborne applications.

Original languageEnglish (US)
Title of host publicationSensing Technologies for Global Health, Military Medicine, Disaster Response, and Environmental Monitoring; and Biometric Technology for Human Identification VIII
DOIs
StatePublished - Jul 6 2011
EventSensing Technologies for Global Health, Military Medicine, Disaster Response, and Environmental Monitoring; and Biometric Technology for Human Identification VIII - Orlando, FL, United States
Duration: Apr 25 2011Apr 27 2011

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume8029
ISSN (Print)0277-786X

Other

OtherSensing Technologies for Global Health, Military Medicine, Disaster Response, and Environmental Monitoring; and Biometric Technology for Human Identification VIII
CountryUnited States
CityOrlando, FL
Period4/25/114/27/11

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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    Khan, A., Sun, K., Miller, D. J., & Zondlo, M. A. (2011). Simultaneous detection of atmospheric nitrous oxide and carbon monoxide using a quantum cascade laser. In Sensing Technologies for Global Health, Military Medicine, Disaster Response, and Environmental Monitoring; and Biometric Technology for Human Identification VIII [80291H] (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 8029). https://doi.org/10.1117/12.884275