Silicon oxide nafion composite membranes for proton-exchange membrane fuel cell operation at 80-140°C

K. T. Adjemian, S. J. Lee, S. Srinivasan, Jay Burton Benziger, Andrew Bruce Bocarsly

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Abstract

Silicon oxide/Nafion composite membranes were studied for operation in hydrogen/oxygen proton-exchange membrane fuel cells (PEMFCs) from 80 to 140°C. The composite membranes were prepared either by an impregnation of Nafion 115 via sol-gel processing of tetraethoxysilane or by preparing a recast film, using solubilized Nafion 115 and a silicon oxide polymer/gel. Tetraethoxysilane, when reacted with water in an acidic medium, undergoes polymerization to form a mixture of SiO2 and siloxane polymer with product hydroxide and ethoxide groups. This material is referred to as SiOs/-OH/-OEt. When Nafion is used as the acidic medium, the SiO2/siloxane polymer forms within the membrane. All composite membranes had a silicon oxide content of less than or equal to 10 wt%. The silicon oxide improved the water retention of the composite membranes, increasing proton conductivity at elevated temperatures. Attenuated total reflectance-Fourier transform infrared spectroscopy and scanning electron microscopy experiments indicated an evenly distributed siloxane polymer of SiO2/-OH/-OEt in the composite membranes. At a potential of 0.4 V, silicon oxide/Nafion 115 composite membranes delivered four times the current density obtained with unmodified Nafion 115 in a H2/O2 PEMFC at 130°C and a pressure of 3 atm. Furthermore, silicon oxide-modified membranes were more robust than the control membranes (unmodified Nafion 115 and recast Nafion), which degraded after high operation temperature and thermal cycling.

Original languageEnglish (US)
Pages (from-to)A256-A261
JournalJournal of the Electrochemical Society
Volume149
Issue number3
DOIs
StatePublished - Mar 2002

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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