Side Chain Redistribution as a Strategy to Boost Organic Electrochemical Transistor Performance and Stability

Maximilian Moser; Tania Cecilia Hidalgo; Jokubas Surgailis; Johannes Gladisch; Sarbani Ghosh; Rajendar Sheelamanthula; Quentin Thiburce; Alexander Giovannitti; Alberto Salleo; Nicola Gasparini; Andrew Wadsworth; Igor Zozoulenko; Magnus Berggren; Eleni Stavrinidou; Sahika Inal; Iain McCulloch

doi:10.1002/adma.202002748

Side Chain Redistribution as a Strategy to Boost Organic Electrochemical Transistor Performance and Stability

Maximilian Moser
, Tania Cecilia Hidalgo
, Jokubas Surgailis
, Johannes Gladisch
, Sarbani Ghosh
, Rajendar Sheelamanthula
, Quentin Thiburce
, Alexander Giovannitti
, Alberto Salleo
, Nicola Gasparini
, Andrew Wadsworth
, Igor Zozoulenko
, Magnus Berggren
, Eleni Stavrinidou
, Sahika Inal
, Iain McCulloch

Research output: Contribution to journal › Article › peer-review

272 Scopus citations

Abstract

A series of glycolated polythiophenes for use in organic electrochemical transistors (OECTs) is designed and synthesized, differing in the distribution of their ethylene glycol chains that are tethered to the conjugated backbone. While side chain redistribution does not have a significant impact on the optoelectronic properties of the polymers, this molecular engineering strategy strongly impacts the water uptake achieved in the polymers. By careful optimization of the water uptake in the polymer films, OECTs with unprecedented steady-state performances in terms of [μC^*] and current retentions up to 98% over 700 electrochemical switching cycles are developed.

Original language	English (US)
Article number	2002748
Journal	Advanced Materials
Volume	32
Issue number	37
DOIs	https://doi.org/10.1002/adma.202002748
State	Published - Sep 1 2020
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Materials Science
Mechanics of Materials
Mechanical Engineering

Keywords

bioelectronics
ethylene-glycol-functionalized polymers
mixed ionic–electronic conduction
organic electrochemical transistors

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10.1002/adma.202002748

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Moser, M., Hidalgo, T. C., Surgailis, J., Gladisch, J., Ghosh, S., Sheelamanthula, R., Thiburce, Q., Giovannitti, A., Salleo, A., Gasparini, N., Wadsworth, A., Zozoulenko, I., Berggren, M., Stavrinidou, E., Inal, S., & McCulloch, I. (2020). Side Chain Redistribution as a Strategy to Boost Organic Electrochemical Transistor Performance and Stability. Advanced Materials, 32(37), Article 2002748. https://doi.org/10.1002/adma.202002748

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title = "Side Chain Redistribution as a Strategy to Boost Organic Electrochemical Transistor Performance and Stability",

abstract = "A series of glycolated polythiophenes for use in organic electrochemical transistors (OECTs) is designed and synthesized, differing in the distribution of their ethylene glycol chains that are tethered to the conjugated backbone. While side chain redistribution does not have a significant impact on the optoelectronic properties of the polymers, this molecular engineering strategy strongly impacts the water uptake achieved in the polymers. By careful optimization of the water uptake in the polymer films, OECTs with unprecedented steady-state performances in terms of [μC*] and current retentions up to 98\% over 700 electrochemical switching cycles are developed.",

keywords = "bioelectronics, ethylene-glycol-functionalized polymers, mixed ionic–electronic conduction, organic electrochemical transistors",

author = "Maximilian Moser and Hidalgo, \{Tania Cecilia\} and Jokubas Surgailis and Johannes Gladisch and Sarbani Ghosh and Rajendar Sheelamanthula and Quentin Thiburce and Alexander Giovannitti and Alberto Salleo and Nicola Gasparini and Andrew Wadsworth and Igor Zozoulenko and Magnus Berggren and Eleni Stavrinidou and Sahika Inal and Iain McCulloch",

note = "Publisher Copyright: {\textcopyright} 2020 The Authors. Published by Wiley-VCH GmbH",

year = "2020",

month = sep,

day = "1",

doi = "10.1002/adma.202002748",

language = "English (US)",

volume = "32",

journal = "Advanced Materials",

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Moser, M, Hidalgo, TC, Surgailis, J, Gladisch, J, Ghosh, S, Sheelamanthula, R, Thiburce, Q, Giovannitti, A, Salleo, A, Gasparini, N, Wadsworth, A, Zozoulenko, I, Berggren, M, Stavrinidou, E, Inal, S & McCulloch, I 2020, 'Side Chain Redistribution as a Strategy to Boost Organic Electrochemical Transistor Performance and Stability', Advanced Materials, vol. 32, no. 37, 2002748. https://doi.org/10.1002/adma.202002748

TY - JOUR

T1 - Side Chain Redistribution as a Strategy to Boost Organic Electrochemical Transistor Performance and Stability

AU - Moser, Maximilian

AU - Hidalgo, Tania Cecilia

AU - Surgailis, Jokubas

AU - Gladisch, Johannes

AU - Ghosh, Sarbani

AU - Sheelamanthula, Rajendar

AU - Thiburce, Quentin

AU - Giovannitti, Alexander

AU - Salleo, Alberto

AU - Gasparini, Nicola

AU - Wadsworth, Andrew

AU - Zozoulenko, Igor

AU - Berggren, Magnus

AU - Stavrinidou, Eleni

AU - Inal, Sahika

AU - McCulloch, Iain

PY - 2020/9/1

Y1 - 2020/9/1

N2 - A series of glycolated polythiophenes for use in organic electrochemical transistors (OECTs) is designed and synthesized, differing in the distribution of their ethylene glycol chains that are tethered to the conjugated backbone. While side chain redistribution does not have a significant impact on the optoelectronic properties of the polymers, this molecular engineering strategy strongly impacts the water uptake achieved in the polymers. By careful optimization of the water uptake in the polymer films, OECTs with unprecedented steady-state performances in terms of [μC*] and current retentions up to 98% over 700 electrochemical switching cycles are developed.

AB - A series of glycolated polythiophenes for use in organic electrochemical transistors (OECTs) is designed and synthesized, differing in the distribution of their ethylene glycol chains that are tethered to the conjugated backbone. While side chain redistribution does not have a significant impact on the optoelectronic properties of the polymers, this molecular engineering strategy strongly impacts the water uptake achieved in the polymers. By careful optimization of the water uptake in the polymer films, OECTs with unprecedented steady-state performances in terms of [μC*] and current retentions up to 98% over 700 electrochemical switching cycles are developed.

KW - bioelectronics

KW - ethylene-glycol-functionalized polymers

KW - mixed ionic–electronic conduction

KW - organic electrochemical transistors

UR - https://www.scopus.com/pages/publications/85088979971

UR - https://www.scopus.com/pages/publications/85088979971#tab=citedBy

U2 - 10.1002/adma.202002748

DO - 10.1002/adma.202002748

M3 - Article

C2 - 32754923

AN - SCOPUS:85088979971

SN - 0935-9648

VL - 32

JO - Advanced Materials

JF - Advanced Materials

IS - 37

M1 - 2002748

ER -

Side Chain Redistribution as a Strategy to Boost Organic Electrochemical Transistor Performance and Stability

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