Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts

Keyphrases

• Diimine 100%
• 1,3-dienes 100%
• Unactivated Olefins 100%
• 1,4-hydrovinylation 100%
• Oxidative Cyclization 66%
• Diene Complexes 66%
• Experiment Analysis 33%
• Labeling Experiment 33%
• Kinetic Analysis 33%
• Antiferromagnetic Coupling 33%
• Alkenes 33%
• Mechanistic Studies 33%
• Well-defined 33%
• Transition State 33%
• Single Component 33%
• Iron Complexes 33%
• High Selectivity 33%
• Deuterium Labeling 33%
• Provided Support 33%
• Catalytic Reaction 33%
• Single Crystal X-ray Diffraction (SCXRD) 33%
• Magnetic Measurements 33%
• Steric Interactions 33%
• Resting State 33%
• Radical Anions 33%
• Isoprene 33%
• 1,5-cyclooctadiene 33%
• Alkene Isomerization 33%
• DFT Calculations 33%
• Hydrogen Elimination 33%
• Fe(IV) 33%
• Precatalyst 33%
• Metallacycles 33%
• Conjugated Dienes 33%
• Skipped Dienes 33%
• High Spin 33%
• Z-olefins 33%

Chemistry

• Alkene 100%
• Hydrovinylation 100%
• Catalyst 100%
• Chemical Oxygen Demand 40%
• Oxidative Cyclization 40%
• Ground State 20%
• Kinetic Method 20%
• Antiferromagnetic 20%
• Mechanistic Study 20%
• Transition State 20%
• Iron Complex 20%
• Spectroscopy 20%
• Single Crystal X-Ray Diffraction 20%
• Radical Anion 20%
• Catalytic Reaction 20%
• Metallacycle 20%
• formation 20%
• pre-catalyst 20%
• Isomerization 20%
• Deuterium 20%
• Density Functional Theory 20%
• Hydrogen 20%