Ruthenium Oxide Nanosheets for Enhanced Oxygen Evolution Catalysis in Acidic Medium

Sourav Laha, Yonghyuk Lee, Filip Podjaski, Daniel Weber, Viola Duppel, Leslie M. Schoop, Florian Pielnhofer, Christoph Scheurer, Kathrin Müller, Ulrich Starke, Karsten Reuter, Bettina V. Lotsch

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29 Scopus citations

Abstract

The fabrication of highly active and robust hexagonal ruthenium oxide nanosheets for the electrocatalytic oxygen evolution reaction (OER) in an acidic environment is reported. The ruthenate nanosheets exhibit the best OER activity of all solution-processed acid medium electrocatalysts reported to date, reaching 10 mA cm −2 at an overpotential of only ≈255 mV. The nanosheets also demonstrate robustness under harsh oxidizing conditions. Theoretical calculations give insights into the OER mechanism and reveal that the edges are the origin of the high OER activity of the nanosheets. Moreover, the post OER analyses indicate, apart from coarsening, no observable change in the morphology of the nanosheets or oxidation states of ruthenium during the electrocatalytic process. Therefore, the present investigation suggests that ruthenate nanosheets are a promising acid medium OER catalyst with application potential in proton exchange membrane electrolyzers and beyond.

Original languageEnglish (US)
Article number1803795
JournalAdvanced Energy Materials
Volume9
Issue number15
DOIs
StatePublished - Apr 18 2019
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Keywords

  • DFT calculations
  • OER mechanism
  • electrocatalysis
  • exfoliation
  • nanosheets
  • oxygen evolution reaction
  • water splitting

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    Laha, S., Lee, Y., Podjaski, F., Weber, D., Duppel, V., Schoop, L. M., Pielnhofer, F., Scheurer, C., Müller, K., Starke, U., Reuter, K., & Lotsch, B. V. (2019). Ruthenium Oxide Nanosheets for Enhanced Oxygen Evolution Catalysis in Acidic Medium. Advanced Energy Materials, 9(15), [1803795]. https://doi.org/10.1002/aenm.201803795