Ring 'flipping' in bis(cyclo-octatetraene)titanium(II); an organometallic intramolecular redox reaction which involves only the geometrical deformation of organic ligands

Jeffrey Schwartz; J. Evan Sadler

doi:10.1039/C39730000172

Ring 'flipping' in bis(cyclo-octatetraene)titanium(II); an organometallic intramolecular redox reaction which involves only the geometrical deformation of organic ligands

Jeffrey Schwartz
, J. Evan Sadler

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A new type of fluxional process for an organometallic system is described for (C₈H₈)₂Ti in which formal oxidation and reduction occurs for the planar and bent C₈H₈ ligand rings, respectively, solely through reciprocal ring bending and flattening, with an activation energy, at 63°, of ΔG^‡ = 16·7 ± 0·2 kcal/mol.

Original language	English (US)
Pages (from-to)	172-173
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39730000172
State	Published - 1973

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39730000172

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title = "Ring 'flipping' in bis(cyclo-octatetraene)titanium(II); an organometallic intramolecular redox reaction which involves only the geometrical deformation of organic ligands",

abstract = "A new type of fluxional process for an organometallic system is described for (C8H8)2Ti in which formal oxidation and reduction occurs for the planar and bent C8H8 ligand rings, respectively, solely through reciprocal ring bending and flattening, with an activation energy, at 63°, of ΔG‡ = 16·7 ± 0·2 kcal/mol.",

author = "Jeffrey Schwartz and Sadler, \{J. Evan\}",

year = "1973",

doi = "10.1039/C39730000172",

language = "English (US)",

pages = "172--173",

journal = "Journal of the Chemical Society D: Chemical Communications",

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publisher = "Chemical Society",

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T1 - Ring 'flipping' in bis(cyclo-octatetraene)titanium(II); an organometallic intramolecular redox reaction which involves only the geometrical deformation of organic ligands

AU - Schwartz, Jeffrey

AU - Sadler, J. Evan

PY - 1973

Y1 - 1973

N2 - A new type of fluxional process for an organometallic system is described for (C8H8)2Ti in which formal oxidation and reduction occurs for the planar and bent C8H8 ligand rings, respectively, solely through reciprocal ring bending and flattening, with an activation energy, at 63°, of ΔG‡ = 16·7 ± 0·2 kcal/mol.

AB - A new type of fluxional process for an organometallic system is described for (C8H8)2Ti in which formal oxidation and reduction occurs for the planar and bent C8H8 ligand rings, respectively, solely through reciprocal ring bending and flattening, with an activation energy, at 63°, of ΔG‡ = 16·7 ± 0·2 kcal/mol.

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UR - https://www.scopus.com/pages/publications/37049137621#tab=citedBy

U2 - 10.1039/C39730000172

DO - 10.1039/C39730000172

M3 - Article

AN - SCOPUS:37049137621

SN - 0022-4936

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EP - 173

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 5

ER -

Ring 'flipping' in bis(cyclo-octatetraene)titanium(II); an organometallic intramolecular redox reaction which involves only the geometrical deformation of organic ligands

Abstract

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