TY - JOUR
T1 - Ring 'flipping' in bis(cyclo-octatetraene)titanium(II); an organometallic intramolecular redox reaction which involves only the geometrical deformation of organic ligands
AU - Schwartz, Jeffrey
AU - Sadler, J. Evan
PY - 1973
Y1 - 1973
N2 - A new type of fluxional process for an organometallic system is described for (C8H8)2Ti in which formal oxidation and reduction occurs for the planar and bent C8H8 ligand rings, respectively, solely through reciprocal ring bending and flattening, with an activation energy, at 63°, of ΔG‡ = 16·7 ± 0·2 kcal/mol.
AB - A new type of fluxional process for an organometallic system is described for (C8H8)2Ti in which formal oxidation and reduction occurs for the planar and bent C8H8 ligand rings, respectively, solely through reciprocal ring bending and flattening, with an activation energy, at 63°, of ΔG‡ = 16·7 ± 0·2 kcal/mol.
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U2 - 10.1039/C39730000172
DO - 10.1039/C39730000172
M3 - Article
AN - SCOPUS:37049137621
SN - 0022-4936
SP - 172
EP - 173
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 5
ER -