Flash vacuum pyrolysis of N-(p-chlorophenoxymethyl)azoles (e.g. 2 and 3) gives ring expanded products (e.g. 4 and 8) formed via N-heteroarylmethyl radicals (e.g. 1 and 6); the mechanism of ring expansion generally involves a novel 'walk'-rearrangement of the radical centre.
|Original language||English (US)|
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - 1993|
All Science Journal Classification (ASJC) codes
- Molecular Medicine