Ring expansion and rearrangement reactions of N-heteroarylmethyl radicals

Jill F. McLellan; Hamish McNab; Thomas W. Muir

doi:10.1039/C39930000839

Ring expansion and rearrangement reactions of N-heteroarylmethyl radicals

Jill F. McLellan, Hamish McNab, Thomas W. Muir

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Flash vacuum pyrolysis of N-(p-chlorophenoxymethyl)azoles (e.g. 2 and 3) gives ring expanded products (e.g. 4 and 8) formed via N-heteroarylmethyl radicals (e.g. 1 and 6); the mechanism of ring expansion generally involves a novel 'walk'-rearrangement of the radical centre.

Original language	English (US)
Pages (from-to)	839-840
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39930000839
State	Published - 1993
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39930000839

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title = "Ring expansion and rearrangement reactions of N-heteroarylmethyl radicals",

abstract = "Flash vacuum pyrolysis of N-(p-chlorophenoxymethyl)azoles (e.g. 2 and 3) gives ring expanded products (e.g. 4 and 8) formed via N-heteroarylmethyl radicals (e.g. 1 and 6); the mechanism of ring expansion generally involves a novel 'walk'-rearrangement of the radical centre.",

author = "McLellan, {Jill F.} and Hamish McNab and Muir, {Thomas W.}",

year = "1993",

doi = "10.1039/C39930000839",

language = "English (US)",

pages = "839--840",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "10",

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TY - JOUR

T1 - Ring expansion and rearrangement reactions of N-heteroarylmethyl radicals

AU - McLellan, Jill F.

AU - McNab, Hamish

AU - Muir, Thomas W.

PY - 1993

Y1 - 1993

N2 - Flash vacuum pyrolysis of N-(p-chlorophenoxymethyl)azoles (e.g. 2 and 3) gives ring expanded products (e.g. 4 and 8) formed via N-heteroarylmethyl radicals (e.g. 1 and 6); the mechanism of ring expansion generally involves a novel 'walk'-rearrangement of the radical centre.

AB - Flash vacuum pyrolysis of N-(p-chlorophenoxymethyl)azoles (e.g. 2 and 3) gives ring expanded products (e.g. 4 and 8) formed via N-heteroarylmethyl radicals (e.g. 1 and 6); the mechanism of ring expansion generally involves a novel 'walk'-rearrangement of the radical centre.

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U2 - 10.1039/C39930000839

DO - 10.1039/C39930000839

M3 - Article

AN - SCOPUS:2942736767

SN - 0022-4936

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 10

ER -

Ring expansion and rearrangement reactions of N-heteroarylmethyl radicals

Abstract

All Science Journal Classification (ASJC) codes

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