Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

Ya Du; Todd K. Hyster; Tomislav Rovis

doi:10.1039/c1cc15843k

Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

Ya Du, Todd K. Hyster, Tomislav Rovis

Research output: Contribution to journal › Article › peer-review

144 Scopus citations

Abstract

An efficient strategy for the oxidative carbonylation of aromatic amides via C-H/N-H activation to form phthalimides using an Rh(iii) catalyst has been developed. The reaction shows a preference for C-H bonds of electron-rich aromatic amides and tolerates a variety of functional groups.

Original language	English (US)
Pages (from-to)	12074-12076
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	44
DOIs	https://doi.org/10.1039/c1cc15843k
State	Published - Nov 28 2011
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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title = "Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide",

abstract = "An efficient strategy for the oxidative carbonylation of aromatic amides via C-H/N-H activation to form phthalimides using an Rh(iii) catalyst has been developed. The reaction shows a preference for C-H bonds of electron-rich aromatic amides and tolerates a variety of functional groups.",

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AU - Du, Ya

AU - Hyster, Todd K.

AU - Rovis, Tomislav

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Y1 - 2011/11/28

N2 - An efficient strategy for the oxidative carbonylation of aromatic amides via C-H/N-H activation to form phthalimides using an Rh(iii) catalyst has been developed. The reaction shows a preference for C-H bonds of electron-rich aromatic amides and tolerates a variety of functional groups.

AB - An efficient strategy for the oxidative carbonylation of aromatic amides via C-H/N-H activation to form phthalimides using an Rh(iii) catalyst has been developed. The reaction shows a preference for C-H bonds of electron-rich aromatic amides and tolerates a variety of functional groups.

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JO - Chemical Communications

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Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

Abstract

All Science Journal Classification (ASJC) codes

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