Repetitive intramolecular substitution (with inversion) at carbon: A new type of fluxional process for an organometallic complex

Kerrie I. Gell; Gregory M. Williams; Jeffrey Schwartz

doi:10.1039/c39800000550

Repetitive intramolecular substitution (with inversion) at carbon: A new type of fluxional process for an organometallic complex

Kerrie I. Gell
, Gregory M. Williams
, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Cp₂(Cl)Zr_AOC(l)HRZr_B(Cl)Cp₂ (Cp = cyclopentadienyl) undergoes a fluxional process which exchanges the O- and C-bonds to Zr_A and Zr_B, respectively, and proceeds by an inversion at C(l).

Original language	English (US)
Pages (from-to)	550-552
Number of pages	3
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/c39800000550
State	Published - 1980

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/c39800000550

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@article{5cfc92a85f294e1e88b3ed678395973c,

title = "Repetitive intramolecular substitution (with inversion) at carbon: A new type of fluxional process for an organometallic complex",

abstract = "Cp2(Cl)ZrAOC(l)HRZrB(Cl)Cp2 (Cp = cyclopentadienyl) undergoes a fluxional process which exchanges the O- and C-bonds to ZrA and ZrB, respectively, and proceeds by an inversion at C(l).",

author = "Gell, \{Kerrie I.\} and Williams, \{Gregory M.\} and Jeffrey Schwartz",

year = "1980",

doi = "10.1039/c39800000550",

language = "English (US)",

pages = "550--552",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "12",

}

TY - JOUR

T1 - Repetitive intramolecular substitution (with inversion) at carbon

T2 - A new type of fluxional process for an organometallic complex

AU - Gell, Kerrie I.

AU - Williams, Gregory M.

AU - Schwartz, Jeffrey

PY - 1980

Y1 - 1980

N2 - Cp2(Cl)ZrAOC(l)HRZrB(Cl)Cp2 (Cp = cyclopentadienyl) undergoes a fluxional process which exchanges the O- and C-bonds to ZrA and ZrB, respectively, and proceeds by an inversion at C(l).

AB - Cp2(Cl)ZrAOC(l)HRZrB(Cl)Cp2 (Cp = cyclopentadienyl) undergoes a fluxional process which exchanges the O- and C-bonds to ZrA and ZrB, respectively, and proceeds by an inversion at C(l).

UR - https://www.scopus.com/pages/publications/37049113690

UR - https://www.scopus.com/pages/publications/37049113690#tab=citedBy

U2 - 10.1039/c39800000550

DO - 10.1039/c39800000550

M3 - Article

AN - SCOPUS:37049113690

SN - 0022-4936

SP - 550

EP - 552

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 12

ER -

Repetitive intramolecular substitution (with inversion) at carbon: A new type of fluxional process for an organometallic complex

Abstract

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