Reductions with Copper Hydride. New Preparative and Mechanistic Aspects

M. F. Semmelhack; R. D. Stauffer

doi:10.1021/jo00912a040

Reductions with Copper Hydride. New Preparative and Mechanistic Aspects

M. F. Semmelhack, R. D. Stauffer

Research output: Contribution to journal › Letter › peer-review

83 Scopus citations

Abstract

Simple copper hydride reagents are described which reduce conjugated carbonyl compounds to the saturated derivatives; a special effect of added sec-butyl alcohol allows reduction of acrylates and labeling experiments establish the sources of the added hydrogens.

Original language	English (US)
Pages (from-to)	3619-3621
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	40
Issue number	24
DOIs	https://doi.org/10.1021/jo00912a040
State	Published - Nov 1 1975
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1021/jo00912a040

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title = "Reductions with Copper Hydride. New Preparative and Mechanistic Aspects",

abstract = "Simple copper hydride reagents are described which reduce conjugated carbonyl compounds to the saturated derivatives; a special effect of added sec-butyl alcohol allows reduction of acrylates and labeling experiments establish the sources of the added hydrogens.",

author = "Semmelhack, \{M. F.\} and Stauffer, \{R. D.\}",

year = "1975",

month = nov,

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doi = "10.1021/jo00912a040",

language = "English (US)",

volume = "40",

pages = "3619--3621",

journal = "Journal of Organic Chemistry",

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T1 - Reductions with Copper Hydride. New Preparative and Mechanistic Aspects

AU - Semmelhack, M. F.

AU - Stauffer, R. D.

PY - 1975/11/1

Y1 - 1975/11/1

N2 - Simple copper hydride reagents are described which reduce conjugated carbonyl compounds to the saturated derivatives; a special effect of added sec-butyl alcohol allows reduction of acrylates and labeling experiments establish the sources of the added hydrogens.

AB - Simple copper hydride reagents are described which reduce conjugated carbonyl compounds to the saturated derivatives; a special effect of added sec-butyl alcohol allows reduction of acrylates and labeling experiments establish the sources of the added hydrogens.

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U2 - 10.1021/jo00912a040

DO - 10.1021/jo00912a040

M3 - Letter

AN - SCOPUS:0000063964

SN - 0022-3263

VL - 40

SP - 3619

EP - 3621

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 24

ER -

Reductions with Copper Hydride. New Preparative and Mechanistic Aspects

Abstract

All Science Journal Classification (ASJC) codes

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