Rapid Vinyl Shifts in Spiro[4.4]polyenes: Verification of the Rate-Determining Step and the Identity of the Migrating Group

Keyphrases

• Rate-determining Step 100%
• Polyenes 100%
• Spiro 100%
• Vinyl 100%
• Trienes 66%
• Structure Determination 33%
• Pyrolysis 33%
• Dimethyl 3 33%
• Tetrazine 33%
• Deuterium Isotope Effect 33%
• Pyrolysis Products 33%
• Alkyl Migration 33%
• X-ray Diffraction Structure 33%
• Sigmatropic Shift 33%
• Pyrolysis Study 33%
• H-shift 33%

Chemistry

• Polyene 100%
• Pyrolysis 100%
• Rate-Determining Step 100%
• X-Ray Diffraction 50%
• Studies of Pyrolysis 50%
• Tetrazine 50%
• Isotope Effect 50%
• Structure Determination 50%
• Deuterium 50%