Abstract
The oxygen atom donor ability of the oxomanganese(v) porphyrin species 1 is comparable to that of myeloperoxidase compound I. This is one of the key findings of the reversible oxygen atom transfer reaction between 1 and bromide ion [Eq. (1)]. The well-behaved equilibrium 1 ⇆ 2 allows definition of the free energy of the oxoMn(v) species.
Original language | English (US) |
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Pages (from-to) | 3849-3851 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 39 |
Issue number | 21 |
DOIs | |
State | Published - Nov 3 2000 |
All Science Journal Classification (ASJC) codes
- General Chemistry
- Catalysis
Keywords
- Enzymes
- Halogens
- Kinetics
- Oxidation
- Porphyrinoids
- Redox chemistry