The oxygen atom donor ability of the oxomanganese(v) porphyrin species 1 is comparable to that of myeloperoxidase compound I. This is one of the key findings of the reversible oxygen atom transfer reaction between 1 and bromide ion [Eq. (1)]. The well-behaved equilibrium 1 ⇆ 2 allows definition of the free energy of the oxoMn(v) species.
|Original language||English (US)|
|Number of pages||3|
|Journal||Angewandte Chemie - International Edition|
|State||Published - Nov 3 2000|
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