Abstract
Recently Lebowitz and Penrose gave a rigorous derivation of the van der Waals-Maxwell theory of the liquid-vapor transition, and showed how the Maxwell equal area-rule could be obtained from a proper statistical mechanical calculation. Their results are quite general - being valid in any number of dimensions and for a broad class of pair potentials - but they were proved only for classical mechanics. In the present work we extend the proof to quantum systems with any statistics - Boltzmann, Bose, or Fermi. One corollary of this extended theorem is a model of a Bose gas with a first-order phase transition.
Original language | English (US) |
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Pages (from-to) | 1016-1024 |
Number of pages | 9 |
Journal | Journal of Mathematical Physics |
Volume | 7 |
Issue number | 6 |
DOIs | |
State | Published - 1966 |
All Science Journal Classification (ASJC) codes
- Statistical and Nonlinear Physics
- Mathematical Physics