Quantum-coherence and correlations in π-conjugated molecules and multichromophoric systems

Research output: Contribution to journalConference article

Abstract

Chemistry is intrinsically founded on quantum mechanical principles and examples of quantum-mechanical phenomena abound on a range of energy and length scales. In this article some examples of quantum-mechanical phenomena that can be probed by optical spectroscopy are discussed. Recent experimental studies of quantumcoherence in electronic energy transfer in ?-conjugated polymers are reported as examples of weak correlations. The nature of the electron-hole binding energy for excitons in organic systems is investigated as a case of intermediate correlations. Possible experimental probes of strong correlations involved in chemical reactions are critically examined in the final section of the paper. 1876-6196

Original languageEnglish (US)
Pages (from-to)82-91
Number of pages10
JournalProcedia Chemistry
Volume3
Issue number1
DOIs
StatePublished - Jan 1 2011
Externally publishedYes
Event22nd Solvay Conference on Chemistry - Quantum Effects in Chemistry and Biology - Brussels, Belgium
Duration: Oct 13 2010Oct 16 2010

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Keywords

  • Binding energy
  • Conjugated polymer
  • Double quantum coherence
  • Electron correlation
  • Energy transfer
  • Exciton

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