Pyridine synthesis from oximes and alkynes via rhodium(iii) catalysis: Cp* and Cpt provide complementary selectivity

Todd K. Hyster; Tomislav Rovis

doi:10.1039/c1cc15248c

Pyridine synthesis from oximes and alkynes via rhodium(iii) catalysis: Cp* and Cp^t provide complementary selectivity

Todd K. Hyster, Tomislav Rovis

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334 Scopus citations

Abstract

The synthesis of pyridines from readily available α,β- unsaturated oximes and alkynes under mild conditions and low temperatures using Rh(iii) catalysis has been developed. It was found that the use of sterically different ligands allows for complementary selectivities to be achieved.

Original language	English (US)
Pages (from-to)	11846-11848
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	43
DOIs	https://doi.org/10.1039/c1cc15248c
State	Published - Nov 21 2011
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/c1cc15248c

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title = "Pyridine synthesis from oximes and alkynes via rhodium(iii) catalysis: Cp* and Cpt provide complementary selectivity",

abstract = "The synthesis of pyridines from readily available α,β- unsaturated oximes and alkynes under mild conditions and low temperatures using Rh(iii) catalysis has been developed. It was found that the use of sterically different ligands allows for complementary selectivities to be achieved.",

author = "Hyster, {Todd K.} and Tomislav Rovis",

year = "2011",

month = nov,

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doi = "10.1039/c1cc15248c",

language = "English (US)",

volume = "47",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Pyridine synthesis from oximes and alkynes via rhodium(iii) catalysis

T2 - Cp* and Cpt provide complementary selectivity

AU - Hyster, Todd K.

AU - Rovis, Tomislav

PY - 2011/11/21

Y1 - 2011/11/21

N2 - The synthesis of pyridines from readily available α,β- unsaturated oximes and alkynes under mild conditions and low temperatures using Rh(iii) catalysis has been developed. It was found that the use of sterically different ligands allows for complementary selectivities to be achieved.

AB - The synthesis of pyridines from readily available α,β- unsaturated oximes and alkynes under mild conditions and low temperatures using Rh(iii) catalysis has been developed. It was found that the use of sterically different ligands allows for complementary selectivities to be achieved.

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DO - 10.1039/c1cc15248c

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SN - 1359-7345

VL - 47

SP - 11846

EP - 11848

JO - Chemical Communications

JF - Chemical Communications

IS - 43

ER -

Pyridine synthesis from oximes and alkynes via rhodium(iii) catalysis: Cp* and Cp^t provide complementary selectivity

Abstract

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