Proton-Coupled Electron Transfer to a Molybdenum Ethylene Complex Yields a β-Agostic Ethyl: Structure, Dynamics and Mechanism

Engineering & Materials Science

• Protons 83%
• Molybdenum 80%
• Ethylene 71%
• Electrons 69%
• Ligands 55%
• Organometallics 41%
• Electronic structure 40%
• Nuclear magnetic resonance 33%
• Olefins 32%
• Protonation 25%
• Isomerization 20%
• Deuterium 19%
• Oxidation-Reduction 18%
• Hydrides 17%
• Isotopes 16%
• Free energy 16%
• Discrete Fourier transforms 15%
• Computational methods 14%
• Labeling 13%
• Temperature 11%
• Experiments 9%
• Gases 7%

Medicine & Life Sciences

• Molybdenum 100%
• ethylene 94%
• Protons 70%
• Electrons 55%
• Alkenes 43%
• Ligands 29%
• Temperature 19%
• Carbon-13 Magnetic Resonance Spectroscopy 19%
• Deuterium 19%
• Proton Magnetic Resonance Spectroscopy 16%
• Isotopes 14%
• Oxidation-Reduction 13%
• Gases 11%
• Kinetics 10%

Chemical Compounds

• Ethyl 49%
• Electron Transfer 48%
• Reaction Yield 28%
• Electronic State 20%
• Ligand 18%
• Terpyridines 16%
• Kinetic Isotope Effect 15%
• Transfer Reaction 12%
• Deuterium(.) 12%
• Metallocene 12%
• Isomerization 10%
• Gibbs Free Energy 10%
• 13C NMR Spectroscopy 10%
• Alkene 9%
• Chemical Transformation 8%
• Probe 8%
• Chemistry 8%
• Gas 7%