Pressure broadening in the 0–4 through 0–7 overtone bands of H35Cl and H37Cl

Mohammad Zughul, Jack Gelfand, Herschel Rabitz, Andrew E. DePristo

Research output: Contribution to journalArticle

15 Scopus citations

Abstract

We have measured the pressure broadening coefficients of a number of rotation-vibration lines in the 0–4 through 0–7 overtone bands of HCl utilizing a Fourier transform spectrometer and a 409 m path length White cell. These data, when included with previous measurements on the fundamental and lower overtone bands, show a systematic variation of pressure broadening with increasing overtone band. This result reflects a change in the collision dynamics between molecules in the upper state of the transition with ground state molecules.

Original languageEnglish (US)
Pages (from-to)371-377
Number of pages7
JournalJournal of Quantitative Spectroscopy and Radiative Transfer
Volume24
Issue number5
DOIs
StatePublished - Jan 1 1980

All Science Journal Classification (ASJC) codes

  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Spectroscopy

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