Preparation of Zirconium(II) Complexes by Ligand-Induced Reductive Elimination. Bis(η5-cyclopentadienyl)bis(phosphine )zirconium( II) Complexes and Their Reactions

Kerrie I. Cell; Jeffrey Schwartz

doi:10.1021/ja00400a033

Preparation of Zirconium(II) Complexes by Ligand-Induced Reductive Elimination. Bis(η⁵-cyclopentadienyl)bis(phosphine )zirconium( II) Complexes and Their Reactions

Kerrie I. Cell, Jeffrey Schwartz

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127 Scopus citations

Abstract

Bis(η⁵-cyclopentadienyl)bis(phosphine)zirconium(II) complexes were prepared by ligand-induced reductive elimination of alkane from bis(η⁵-cyclopentadienyl)chloroalkylzirconium(IV) precursors. Reactions of these species with H₂, CO, other phosphines, acetylenes, olefins, arenes, and organic halides are described.

Original language	English (US)
Pages (from-to)	2687-2695
Number of pages	9
Journal	Journal of the American Chemical Society
Volume	103
Issue number	10
DOIs	https://doi.org/10.1021/ja00400a033
State	Published - May 1981

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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title = "Preparation of Zirconium(II) Complexes by Ligand-Induced Reductive Elimination. Bis(η5-cyclopentadienyl)bis(phosphine )zirconium( II) Complexes and Their Reactions",

abstract = "Bis(η5-cyclopentadienyl)bis(phosphine)zirconium(II) complexes were prepared by ligand-induced reductive elimination of alkane from bis(η5-cyclopentadienyl)chloroalkylzirconium(IV) precursors. Reactions of these species with H2, CO, other phosphines, acetylenes, olefins, arenes, and organic halides are described.",

author = "Cell, {Kerrie I.} and Jeffrey Schwartz",

year = "1981",

month = may,

doi = "10.1021/ja00400a033",

language = "English (US)",

volume = "103",

pages = "2687--2695",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

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T1 - Preparation of Zirconium(II) Complexes by Ligand-Induced Reductive Elimination. Bis(η5-cyclopentadienyl)bis(phosphine )zirconium( II) Complexes and Their Reactions

AU - Cell, Kerrie I.

AU - Schwartz, Jeffrey

PY - 1981/5

Y1 - 1981/5

N2 - Bis(η5-cyclopentadienyl)bis(phosphine)zirconium(II) complexes were prepared by ligand-induced reductive elimination of alkane from bis(η5-cyclopentadienyl)chloroalkylzirconium(IV) precursors. Reactions of these species with H2, CO, other phosphines, acetylenes, olefins, arenes, and organic halides are described.

AB - Bis(η5-cyclopentadienyl)bis(phosphine)zirconium(II) complexes were prepared by ligand-induced reductive elimination of alkane from bis(η5-cyclopentadienyl)chloroalkylzirconium(IV) precursors. Reactions of these species with H2, CO, other phosphines, acetylenes, olefins, arenes, and organic halides are described.

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JF - Journal of the American Chemical Society

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ER -

Preparation of Zirconium(II) Complexes by Ligand-Induced Reductive Elimination. Bis(η⁵-cyclopentadienyl)bis(phosphine )zirconium( II) Complexes and Their Reactions

Abstract

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