Preparation of Zirconium(II) Complexes by Ligand-Induced Reductive Elimination. Bis(η5-cyclopentadienyl)bis(phosphine )zirconium( II) Complexes and Their Reactions

Kerrie I. Cell, Jeffrey Schwartz

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121 Scopus citations

Abstract

Bis(η5-cyclopentadienyl)bis(phosphine)zirconium(II) complexes were prepared by ligand-induced reductive elimination of alkane from bis(η5-cyclopentadienyl)chloroalkylzirconium(IV) precursors. Reactions of these species with H2, CO, other phosphines, acetylenes, olefins, arenes, and organic halides are described.

Original languageEnglish (US)
Pages (from-to)2687-2695
Number of pages9
JournalJournal of the American Chemical Society
Volume103
Issue number10
DOIs
StatePublished - May 1981

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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