Preparation and structure of chiral carbene complexes of manganese and iron from terminal alkynes

M. F. Semmelhack, Andreas Lindenschmidt, D. Ho

Research output: Contribution to journalArticle

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Abstract

Chiral-at-the-metal Fischer carbene complexes are prepared by reaction of coordinatively unsaturated Cp(NO)(Ph3P)Mn(+) or Cp(CO)(Ph3P)Fe(+) by intramolecular rearrangement of hydroxyalkyner rearrangement of hydroxyalkynetion of methyl alcohol with TMS-acetylene.

Original languageEnglish (US)
Pages (from-to)4114-4117
Number of pages4
JournalOrganometallics
Volume20
Issue number19
DOIs
StatePublished - Sep 17 2001

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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