Preparation and structure of chiral carbene complexes of manganese and iron from terminal alkynes

M. F. Semmelhack; Andreas Lindenschmidt; D. Ho

doi:10.1021/om010507y

Preparation and structure of chiral carbene complexes of manganese and iron from terminal alkynes

M. F. Semmelhack, Andreas Lindenschmidt, D. Ho

Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Chiral-at-the-metal Fischer carbene complexes are prepared by reaction of coordinatively unsaturated Cp(NO)(Ph₃P)Mn(+) or Cp(CO)(Ph₃P)Fe(+) by intramolecular rearrangement of hydroxyalkyner rearrangement of hydroxyalkynetion of methyl alcohol with TMS-acetylene.

Original language	English (US)
Pages (from-to)	4114-4117
Number of pages	4
Journal	Organometallics
Volume	20
Issue number	19
DOIs	https://doi.org/10.1021/om010507y
State	Published - Sep 17 2001

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om010507y

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title = "Preparation and structure of chiral carbene complexes of manganese and iron from terminal alkynes",

abstract = "Chiral-at-the-metal Fischer carbene complexes are prepared by reaction of coordinatively unsaturated Cp(NO)(Ph3P)Mn(+) or Cp(CO)(Ph3P)Fe(+) by intramolecular rearrangement of hydroxyalkyner rearrangement of hydroxyalkynetion of methyl alcohol with TMS-acetylene.",

author = "Semmelhack, {M. F.} and Andreas Lindenschmidt and D. Ho",

year = "2001",

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T1 - Preparation and structure of chiral carbene complexes of manganese and iron from terminal alkynes

AU - Semmelhack, M. F.

AU - Lindenschmidt, Andreas

AU - Ho, D.

PY - 2001/9/17

Y1 - 2001/9/17

N2 - Chiral-at-the-metal Fischer carbene complexes are prepared by reaction of coordinatively unsaturated Cp(NO)(Ph3P)Mn(+) or Cp(CO)(Ph3P)Fe(+) by intramolecular rearrangement of hydroxyalkyner rearrangement of hydroxyalkynetion of methyl alcohol with TMS-acetylene.

AB - Chiral-at-the-metal Fischer carbene complexes are prepared by reaction of coordinatively unsaturated Cp(NO)(Ph3P)Mn(+) or Cp(CO)(Ph3P)Fe(+) by intramolecular rearrangement of hydroxyalkyner rearrangement of hydroxyalkynetion of methyl alcohol with TMS-acetylene.

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U2 - 10.1021/om010507y

DO - 10.1021/om010507y

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AN - SCOPUS:0035904265

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JO - Organometallics

JF - Organometallics

IS - 19

ER -

Preparation and structure of chiral carbene complexes of manganese and iron from terminal alkynes

Abstract

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