Chiral-at-the-metal Fischer carbene complexes are prepared by reaction of coordinatively unsaturated Cp(NO)(Ph3P)Mn(+) or Cp(CO)(Ph3P)Fe(+) by intramolecular rearrangement of hydroxyalkyner rearrangement of hydroxyalkynetion of methyl alcohol with TMS-acetylene.
|Original language||English (US)|
|Number of pages||4|
|State||Published - Sep 17 2001|
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry