Poly[(μ3-O-ethyl dithiocarbonato-κ5O,S:S, S′:S′)-[(1,10-phenanthroline-κ2N,N′) potassium(I)]]

Sreekumari P. Nair; Tihana Mirkovic; Gregory D. Scholes; Alan J. Lough

doi:10.1107/S1600536806017636

Poly[(μ₃-O-ethyl dithiocarbonato-κ⁵O,S:S, S′:S′)-[(1,10-phenanthroline-κ²N,N′) potassium(I)]]

Sreekumari P. Nair, Tihana Mirkovic, Gregory D. Scholes, Alan J. Lough

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, [K(C₃H₅OS₂)(C ₁₂H₈N₂)]_n, was prepared from potassium ethylxanthate and 1,10-phenanthroline. A one-dimensional structure is formed via coordination to a K^I atom from symmetry-unique and symmetry-related atoms through four S, one O and two N atoms. The coordination geometry is best described as distorted pentagonal-bipyramidal. In the crystal structure, significant π-π stacking interactions connect one-dimensional chains into sheets perpendicular to the b axis.

Original language	English (US)
Pages (from-to)	m1317-m1319
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	6
DOIs	https://doi.org/10.1107/S1600536806017636
State	Published - Jun 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{f378bc89b9b94aaabf6a6ad1d9462dae,

title = "Poly[(μ3-O-ethyl dithiocarbonato-κ5O,S:S, S′:S′)-[(1,10-phenanthroline-κ2N,N′) potassium(I)]]",

abstract = "The title compound, [K(C3H5OS2)(C 12H8N2)]n, was prepared from potassium ethylxanthate and 1,10-phenanthroline. A one-dimensional structure is formed via coordination to a KI atom from symmetry-unique and symmetry-related atoms through four S, one O and two N atoms. The coordination geometry is best described as distorted pentagonal-bipyramidal. In the crystal structure, significant π-π stacking interactions connect one-dimensional chains into sheets perpendicular to the b axis.",

author = "Nair, {Sreekumari P.} and Tihana Mirkovic and Scholes, {Gregory D.} and Lough, {Alan J.}",

year = "2006",

month = jun,

doi = "10.1107/S1600536806017636",

language = "English (US)",

volume = "62",

pages = "m1317--m1319",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "6",

}

TY - JOUR

T1 - Poly[(μ3-O-ethyl dithiocarbonato-κ5O,S:S, S′:S′)-[(1,10-phenanthroline-κ2N,N′) potassium(I)]]

AU - Nair, Sreekumari P.

AU - Mirkovic, Tihana

AU - Scholes, Gregory D.

AU - Lough, Alan J.

PY - 2006/6

Y1 - 2006/6

N2 - The title compound, [K(C3H5OS2)(C 12H8N2)]n, was prepared from potassium ethylxanthate and 1,10-phenanthroline. A one-dimensional structure is formed via coordination to a KI atom from symmetry-unique and symmetry-related atoms through four S, one O and two N atoms. The coordination geometry is best described as distorted pentagonal-bipyramidal. In the crystal structure, significant π-π stacking interactions connect one-dimensional chains into sheets perpendicular to the b axis.

AB - The title compound, [K(C3H5OS2)(C 12H8N2)]n, was prepared from potassium ethylxanthate and 1,10-phenanthroline. A one-dimensional structure is formed via coordination to a KI atom from symmetry-unique and symmetry-related atoms through four S, one O and two N atoms. The coordination geometry is best described as distorted pentagonal-bipyramidal. In the crystal structure, significant π-π stacking interactions connect one-dimensional chains into sheets perpendicular to the b axis.

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U2 - 10.1107/S1600536806017636

DO - 10.1107/S1600536806017636

M3 - Article

AN - SCOPUS:33744999386

SN - 1600-5368

VL - 62

SP - m1317-m1319

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

Poly[(μ₃-O-ethyl dithiocarbonato-κ⁵O,S:S, S′:S′)-[(1,10-phenanthroline-κ²N,N′) potassium(I)]]

Abstract

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