Poly[(μ3-O-ethyl dithiocarbonato-κ5O,S:S, S′:S′)-[(1,10-phenanthroline-κ2N,N′) potassium(I)]]

Sreekumari P. Nair, Tihana Mirkovic, Gregory D. Scholes, Alan J. Lough

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The title compound, [K(C3H5OS2)(C 12H8N2)]n, was prepared from potassium ethylxanthate and 1,10-phenanthroline. A one-dimensional structure is formed via coordination to a KI atom from symmetry-unique and symmetry-related atoms through four S, one O and two N atoms. The coordination geometry is best described as distorted pentagonal-bipyramidal. In the crystal structure, significant π-π stacking interactions connect one-dimensional chains into sheets perpendicular to the b axis.

Original languageEnglish (US)
Pages (from-to)m1317-m1319
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number6
DOIs
StatePublished - Jun 1 2006
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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