A series of planar aryl-substituted bis(imino)pyridine cobalt azide complexes were prepared and evaluated as synthetic precursors for the corresponding cobalt nitrido compounds. Thermolysis or photolysis of two examples resulted in intramolecular C-H activation of the benzylic positions of the aryl substituents. For the mesityl-substituted compound, C-H activation by the putative nitride resulted in formation of a neutral imine ligand and modification of the chelate by hydrogen transfer to the imine carbon.
|Original language||English (US)|
|Number of pages||3|
|Journal||Journal of the American Chemical Society|
|State||Published - Nov 24 2010|
All Science Journal Classification (ASJC) codes
- Colloid and Surface Chemistry