Photoinduced charge flow inside an iron porphyrazine complex

Longteng Tang, Liangdong Zhu, Maraia E. Ener, Hongxin Gao, Yanli Wang, John T. Groves, Thomas G. Spiro, Chong Fang

Research output: Contribution to journalArticlepeer-review

8 Scopus citations


Tracking inorganic photochemistry with high resolution poses considerable challenges. Here, sub-picosecond electronic and structural motions and MLCT/d-d intersystem crossing in a cationic iron-porphyrazine are probed using ultrafast transient absorption, stimulated Raman spectroscopy, and quantum calculations. By delineating photoinduced energy relaxation, strategies for extending the lifetime of MLCT state are discussed.

Original languageEnglish (US)
Pages (from-to)13606-13609
Number of pages4
JournalChemical Communications
Issue number90
StatePublished - 2019

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • General Chemistry
  • Ceramics and Composites
  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Catalysis


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