Photoinduced charge flow inside an iron porphyrazine complex

Longteng Tang, Liangdong Zhu, Maraia E. Ener, Hongxin Gao, Yanli Wang, John T. Groves, Thomas G. Spiro, Chong Fang

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

Tracking inorganic photochemistry with high resolution poses considerable challenges. Here, sub-picosecond electronic and structural motions and MLCT/d-d intersystem crossing in a cationic iron-porphyrazine are probed using ultrafast transient absorption, stimulated Raman spectroscopy, and quantum calculations. By delineating photoinduced energy relaxation, strategies for extending the lifetime of MLCT state are discussed.

Original languageEnglish (US)
Pages (from-to)13606-13609
Number of pages4
JournalChemical Communications
Volume55
Issue number90
DOIs
StatePublished - Jan 1 2019

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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  • Cite this

    Tang, L., Zhu, L., Ener, M. E., Gao, H., Wang, Y., Groves, J. T., Spiro, T. G., & Fang, C. (2019). Photoinduced charge flow inside an iron porphyrazine complex. Chemical Communications, 55(90), 13606-13609. https://doi.org/10.1039/c9cc06193b