(Phenoxyimine)nickel-Catalyzed C(sp²)-C(sp³) Suzuki-Miyaura Cross-Coupling: Evidence for a Recovering Radical Chain Mechanism

Keyphrases

• Nickel-catalyzed 100%
• Suzuki-Miyaura Coupling 100%
• Nickel(II) 100%
• Radical Chain Mechanism 100%
• Phenoxy-imine 100%
• Aryl 66%
• Alkyl Bromide 50%
• Radical Chain 50%
• Hetero 33%
• Potassium 33%
• Reductive Elimination 33%
• Resting State 33%
• Precatalyst 33%
• Arylboronic Acids 33%
• Atom Abstraction 33%
• Nickel(I) 33%
• Nickel(0) 33%
• Radical Propagation 16%
• NMR Spectroscopy 16%
• Product Formation 16%
• Percentage Yield 16%
• Long-lived 16%
• EPR Spectroscopy 16%
• Cross-coupling Reaction 16%
• Kinetic Study 16%
• Organic Radicals 16%
• Catalytic Cycle 16%
• Alkyl Radicals 16%
• Regeneration 16%
• Chain Propagation 16%
• Activation Mechanism 16%
• Transmetalation 16%
• Catalyst Activation 16%
• Bromine Atom 16%
• Recovery Process 16%
• β-hydride Elimination 16%
• Halogen Atoms 16%
• Aryl Compounds 16%
• Odd Electrons 16%
• Aryl Complexes 16%
• Radical Capture 16%
• Chain Processes 16%
• Nickel Intermediates 16%
• Catalyst Recovery 16%

Chemistry

• Bromine Atom 50%