Pb3Sr3Cu3O8+δCl: A new layered copper oxychloride

R. J. Cava, P. Bordet, J. J. Capponi, C. Chaillout, J. Chenavas, T. Fournier, E. A. Hewat, J. L. Hodeau, J. P. Levy, M. Marezio, B. Batlogg, L. W. Rupp

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Abstract

The crystal structure and basic properties of a new layered copper oxychloride, Pb3Sr3Cu3O8+δCl, are described. The new structure type is related to that of Pb2Sr2RECu3O8+δ, with the RE (rare-earth) layer replaced by an (Sr, Pb)-Cl-(Sr, Pb) layer. A wide range of oxygen stoichiometry is observed. The new compound has the planes of CuO5 pyramids required for high-Tc superconductivity, but we have been unable to introduce enough (positive or negative) charge to drive it superconducting.

Original languageEnglish (US)
Pages (from-to)67-74
Number of pages8
JournalPhysica C: Superconductivity and its applications
Volume167
Issue number1-2
DOIs
StatePublished - Apr 15 1990
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering

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    Cava, R. J., Bordet, P., Capponi, J. J., Chaillout, C., Chenavas, J., Fournier, T., Hewat, E. A., Hodeau, J. L., Levy, J. P., Marezio, M., Batlogg, B., & Rupp, L. W. (1990). Pb3Sr3Cu3O8+δCl: A new layered copper oxychloride. Physica C: Superconductivity and its applications, 167(1-2), 67-74. https://doi.org/10.1016/0921-4534(90)90487-Y