Partial oxidation of olefins by molecular oxygen catalysed by (alumina)Rh(O2). Part 2

Jeffrey Schwartz; Jeffrey W. McMillan; H. Eric Fischer

doi:10.1016/0304-5102(92)80261-E

Partial oxidation of olefins by molecular oxygen catalysed by (alumina)Rh(O₂). Part 2

Jeffrey Schwartz, Jeffrey W. McMillan, H. Eric Fischer

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Selective partial oxidation of a series of olefins was accomplished using molecular oxygen, catalysed by (alumina)Rh(O₂). Ketones were the major products; no allylic oxidation was noted, and little combustion or double-bond cleavage was observed. A mechanism involving a carbocationic intermediate is proposed; competitive trapping to either coordinated glycolate or coordinated epoxide is suggested to give the observed ketonic products.

Original language	English (US)
Pages (from-to)	443-450
Number of pages	8
Journal	Journal of Molecular Catalysis
Volume	74
Issue number	1-3
DOIs	https://doi.org/10.1016/0304-5102(92)80261-E
State	Published - Jul 8 1992

All Science Journal Classification (ASJC) codes

Engineering(all)

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title = "Partial oxidation of olefins by molecular oxygen catalysed by (alumina)Rh(O2). Part 2",

abstract = "Selective partial oxidation of a series of olefins was accomplished using molecular oxygen, catalysed by (alumina)Rh(O2). Ketones were the major products; no allylic oxidation was noted, and little combustion or double-bond cleavage was observed. A mechanism involving a carbocationic intermediate is proposed; competitive trapping to either coordinated glycolate or coordinated epoxide is suggested to give the observed ketonic products.",

author = "Jeffrey Schwartz and McMillan, {Jeffrey W.} and Fischer, {H. Eric}",

note = "Funding Information: The authors thank the National Science Foundation for support of this research. They also thank Prof. Luigi M. Venanzi for his generous gift of [Rh(CH3CN)3(Triphos)]3+[CF3S03-b·",

year = "1992",

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doi = "10.1016/0304-5102(92)80261-E",

language = "English (US)",

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pages = "443--450",

journal = "Journal of Molecular Catalysis",

issn = "0304-5102",

publisher = "Elsevier BV",

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T1 - Partial oxidation of olefins by molecular oxygen catalysed by (alumina)Rh(O2). Part 2

AU - Schwartz, Jeffrey

AU - McMillan, Jeffrey W.

AU - Fischer, H. Eric

N1 - Funding Information: The authors thank the National Science Foundation for support of this research. They also thank Prof. Luigi M. Venanzi for his generous gift of [Rh(CH3CN)3(Triphos)]3+[CF3S03-b·

PY - 1992/7/8

Y1 - 1992/7/8

N2 - Selective partial oxidation of a series of olefins was accomplished using molecular oxygen, catalysed by (alumina)Rh(O2). Ketones were the major products; no allylic oxidation was noted, and little combustion or double-bond cleavage was observed. A mechanism involving a carbocationic intermediate is proposed; competitive trapping to either coordinated glycolate or coordinated epoxide is suggested to give the observed ketonic products.

AB - Selective partial oxidation of a series of olefins was accomplished using molecular oxygen, catalysed by (alumina)Rh(O2). Ketones were the major products; no allylic oxidation was noted, and little combustion or double-bond cleavage was observed. A mechanism involving a carbocationic intermediate is proposed; competitive trapping to either coordinated glycolate or coordinated epoxide is suggested to give the observed ketonic products.

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U2 - 10.1016/0304-5102(92)80261-E

DO - 10.1016/0304-5102(92)80261-E

M3 - Article

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VL - 74

SP - 443

EP - 450

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

SN - 0304-5102

IS - 1-3