Partial oxidation of olefins by molecular oxygen catalysed by (alumina)Rh(O2). Part 2

Jeffrey Schwartz; Jeffrey W. McMillan; H. Eric Fischer

doi:10.1016/0304-5102(92)80261-E

Partial oxidation of olefins by molecular oxygen catalysed by (alumina)Rh(O₂). Part 2

Jeffrey Schwartz, Jeffrey W. McMillan, H. Eric Fischer

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Selective partial oxidation of a series of olefins was accomplished using molecular oxygen, catalysed by (alumina)Rh(O₂). Ketones were the major products; no allylic oxidation was noted, and little combustion or double-bond cleavage was observed. A mechanism involving a carbocationic intermediate is proposed; competitive trapping to either coordinated glycolate or coordinated epoxide is suggested to give the observed ketonic products.

Original language	English (US)
Pages (from-to)	443-450
Number of pages	8
Journal	Journal of Molecular Catalysis
Volume	74
Issue number	1-3
DOIs	https://doi.org/10.1016/0304-5102(92)80261-E
State	Published - Jul 8 1992

All Science Journal Classification (ASJC) codes

Engineering(all)

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abstract = "Selective partial oxidation of a series of olefins was accomplished using molecular oxygen, catalysed by (alumina)Rh(O2). Ketones were the major products; no allylic oxidation was noted, and little combustion or double-bond cleavage was observed. A mechanism involving a carbocationic intermediate is proposed; competitive trapping to either coordinated glycolate or coordinated epoxide is suggested to give the observed ketonic products.",

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AU - McMillan, Jeffrey W.

AU - Fischer, H. Eric

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N2 - Selective partial oxidation of a series of olefins was accomplished using molecular oxygen, catalysed by (alumina)Rh(O2). Ketones were the major products; no allylic oxidation was noted, and little combustion or double-bond cleavage was observed. A mechanism involving a carbocationic intermediate is proposed; competitive trapping to either coordinated glycolate or coordinated epoxide is suggested to give the observed ketonic products.

AB - Selective partial oxidation of a series of olefins was accomplished using molecular oxygen, catalysed by (alumina)Rh(O2). Ketones were the major products; no allylic oxidation was noted, and little combustion or double-bond cleavage was observed. A mechanism involving a carbocationic intermediate is proposed; competitive trapping to either coordinated glycolate or coordinated epoxide is suggested to give the observed ketonic products.

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