Partial oxidation of light alkanes by periodate and chloride salts

Steven E. Kalman; Dominik Munz; George C. Fortman; Nicholas C. Boaz; John Taylor Groves; T. Brent Gunnoe

doi:10.1039/c5dt00558b

Partial oxidation of light alkanes by periodate and chloride salts

Steven E. Kalman, Dominik Munz, George C. Fortman, Nicholas C. Boaz, John Taylor Groves, T. Brent Gunnoe

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19 Scopus citations

Abstract

The efficient and selective partial oxidation of light alkanes using potassium periodate and potassium chloride is reported. Yields of methane functionalization in trifluoroacetic acid reach >40% with high selectivity for methyl trifluoroacetate. Periodate and chloride also functionalize ethane and propane in good yields (>20%).

Original language	English (US)
Pages (from-to)	5294-5298
Number of pages	5
Journal	Dalton Transactions
Volume	44
Issue number	12
DOIs	https://doi.org/10.1039/c5dt00558b
State	Published - Mar 28 2015

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/c5dt00558b

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title = "Partial oxidation of light alkanes by periodate and chloride salts",

abstract = "The efficient and selective partial oxidation of light alkanes using potassium periodate and potassium chloride is reported. Yields of methane functionalization in trifluoroacetic acid reach >40\% with high selectivity for methyl trifluoroacetate. Periodate and chloride also functionalize ethane and propane in good yields (>20\%).",

author = "Kalman, \{Steven E.\} and Dominik Munz and Fortman, \{George C.\} and Boaz, \{Nicholas C.\} and Groves, \{John Taylor\} and Gunnoe, \{T. Brent\}",

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T1 - Partial oxidation of light alkanes by periodate and chloride salts

AU - Kalman, Steven E.

AU - Munz, Dominik

AU - Fortman, George C.

AU - Boaz, Nicholas C.

AU - Groves, John Taylor

AU - Gunnoe, T. Brent

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/3/28

Y1 - 2015/3/28

N2 - The efficient and selective partial oxidation of light alkanes using potassium periodate and potassium chloride is reported. Yields of methane functionalization in trifluoroacetic acid reach >40% with high selectivity for methyl trifluoroacetate. Periodate and chloride also functionalize ethane and propane in good yields (>20%).

AB - The efficient and selective partial oxidation of light alkanes using potassium periodate and potassium chloride is reported. Yields of methane functionalization in trifluoroacetic acid reach >40% with high selectivity for methyl trifluoroacetate. Periodate and chloride also functionalize ethane and propane in good yields (>20%).

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U2 - 10.1039/c5dt00558b

DO - 10.1039/c5dt00558b

M3 - Article

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AN - SCOPUS:84924872627

SN - 1477-9226

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 12

ER -

Partial oxidation of light alkanes by periodate and chloride salts

Abstract

All Science Journal Classification (ASJC) codes

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