Paramagnetic susceptibility of disordered N-methyl-phenazinium tetracyanoquinodimethanide

The organic charge-transfer salt N-methyl-phenazinium tetracyanoquinodimethanide is described in terms of a one-dimensional disordered Hubbard model. For low temperatures and small transfer integrals this model reduces to a disordered Heisenberg anti-ferromagnet. The magnetic susceptibility of the latter can be described adequately by the disordered classical Heisenberg model. Fitting of susceptibility data by the one-dimensional classical Heisenberg model provides us with values of t=0.055 eV, Ueff=0.130 eV, and σ=0.136 eV for the parameters of the original Hubbard Hamiltonian.