TY - JOUR
T1 - Packing of Russian doll clusters to form a nanometer-scale CsCl-type compound in a Cr-Zn-Sn complex metallic alloy
AU - Xie, Weiwei
AU - Cava, Robert J.
AU - Miller, Gordon J.
N1 - Publisher Copyright:
© 2017 The Royal Society of Chemistry.
PY - 2017
Y1 - 2017
N2 - The new complex intermetallic alloy, Cr22Zn72Sn24, with a giant cubic unit cell (space group Fm3c, Z = 8, Pearson symbol cF944 with a = 25.083(3) Å) is reported. The structure can be described as a CsCl-type packing of two "Russian Doll" type intermetallic clusters: a 99-atom cluster, Cr(Cr8Zn6)(Sn)24(Zn)60, composed of a central Cr atom encapsulated by three shells: a distorted rhombic dodecahedron, a snub-cube, and a rhombi-icosidodecahedron; and a 55-atom cluster, Cr(Zn)12(Zn)30(Zn)12, also composed of a central Cr atom, but now surrounded by three different shells: an icosahedron, an icosidodecahedron, and a larger icosahedron. The two distinct clusters can be considered as "superatoms" that form the resulting nanometer-scale CsCl-type structure. Evaluating the electronic structure of this complex alloy structure yielded an alternative description, involving a 3-d network of vertex-connected, Cr-centered icosahedra and fragments of bcc metals. This description closely parallels the effective chemical bonding interactions, allowing for an understanding of the stability of this CMA. Magnetic and Seebeck coefficient measurements on self-flux grown crystals of Cr22Zn72Sn24 show it to be paramagnetic and metallic, in agreement with the results of electronic structure calculations.
AB - The new complex intermetallic alloy, Cr22Zn72Sn24, with a giant cubic unit cell (space group Fm3c, Z = 8, Pearson symbol cF944 with a = 25.083(3) Å) is reported. The structure can be described as a CsCl-type packing of two "Russian Doll" type intermetallic clusters: a 99-atom cluster, Cr(Cr8Zn6)(Sn)24(Zn)60, composed of a central Cr atom encapsulated by three shells: a distorted rhombic dodecahedron, a snub-cube, and a rhombi-icosidodecahedron; and a 55-atom cluster, Cr(Zn)12(Zn)30(Zn)12, also composed of a central Cr atom, but now surrounded by three different shells: an icosahedron, an icosidodecahedron, and a larger icosahedron. The two distinct clusters can be considered as "superatoms" that form the resulting nanometer-scale CsCl-type structure. Evaluating the electronic structure of this complex alloy structure yielded an alternative description, involving a 3-d network of vertex-connected, Cr-centered icosahedra and fragments of bcc metals. This description closely parallels the effective chemical bonding interactions, allowing for an understanding of the stability of this CMA. Magnetic and Seebeck coefficient measurements on self-flux grown crystals of Cr22Zn72Sn24 show it to be paramagnetic and metallic, in agreement with the results of electronic structure calculations.
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U2 - 10.1039/c7tc01967j
DO - 10.1039/c7tc01967j
M3 - Article
AN - SCOPUS:85026512865
SN - 2050-7534
VL - 5
SP - 7215
EP - 7221
JO - Journal of Materials Chemistry C
JF - Journal of Materials Chemistry C
IS - 29
ER -