TY - JOUR
T1 - Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis
T2 - Formation of Quaternary Centers by Redox-Neutral Fragment Coupling
AU - Nawrat, Christopher C.
AU - Jamison, Christopher R.
AU - Slutskyy, Yuriy
AU - MacMillan, David W.C.
AU - Overman, Larry E.
N1 - Publisher Copyright:
© 2015 American Chemical Society.
PY - 2015/9/9
Y1 - 2015/9/9
N2 - Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient alkenes is achieved.
AB - Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient alkenes is achieved.
UR - http://www.scopus.com/inward/record.url?scp=84941249106&partnerID=8YFLogxK
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U2 - 10.1021/jacs.5b07678
DO - 10.1021/jacs.5b07678
M3 - Article
C2 - 26322524
AN - SCOPUS:84941249106
SN - 0002-7863
VL - 137
SP - 11270
EP - 11273
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 35
ER -