Organometallic chemistry at the interface with materials science

Jeffrey Schwartz; Steven L. Bernasek

doi:10.1016/S0920-5861(00)00599-X

Organometallic chemistry at the interface with materials science

Jeffrey Schwartz, Steven L. Bernasek

Research output: Contribution to journal › Conference article › peer-review

13 Scopus citations

Abstract

Metal alkoxides are precursors of interfacial species which can be used to enhance interactions between dissimilar components of a composite. Metal alkoxides can react with surface hydroxyl groups of metal oxides or oxidized metals to give covalently bound surface alkoxide species through protolytic loss of one or several alkoxide groups. Because of the reactivity of any remaining alkoxide ligands in the coordination sphere of these surface complexes, a variety of composites can be prepared by ligand exchange.

Original language	English (US)
Pages (from-to)	3-13
Number of pages	11
Journal	Catalysis Today
Volume	66
Issue number	1
DOIs	https://doi.org/10.1016/S0920-5861(00)00599-X
State	Published - Mar 15 2001
Event	Nano-Structured Materials and Their Catalytic Funtions - Sapporo, Japan Duration: Dec 4 1999 → Dec 7 1999

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

Metal alkoxides
Metathesis
Organometallic chemical vapor deposition
Quartz crystal microbalance
Surface organometallic chemistry

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10.1016/S0920-5861(00)00599-X

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title = "Organometallic chemistry at the interface with materials science",

abstract = "Metal alkoxides are precursors of interfacial species which can be used to enhance interactions between dissimilar components of a composite. Metal alkoxides can react with surface hydroxyl groups of metal oxides or oxidized metals to give covalently bound surface alkoxide species through protolytic loss of one or several alkoxide groups. Because of the reactivity of any remaining alkoxide ligands in the coordination sphere of these surface complexes, a variety of composites can be prepared by ligand exchange.",

keywords = "Metal alkoxides, Metathesis, Organometallic chemical vapor deposition, Quartz crystal microbalance, Surface organometallic chemistry",

author = "Jeffrey Schwartz and Bernasek, {Steven L.}",

note = "Funding Information: The authors acknowledge the National Science Foundation, the New Jersey Center for Optoelectronics, and the Lord Corporation for support of the research described herein.; Nano-Structured Materials and Their Catalytic Funtions ; Conference date: 04-12-1999 Through 07-12-1999",

year = "2001",

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doi = "10.1016/S0920-5861(00)00599-X",

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TY - JOUR

T1 - Organometallic chemistry at the interface with materials science

AU - Schwartz, Jeffrey

AU - Bernasek, Steven L.

N1 - Funding Information: The authors acknowledge the National Science Foundation, the New Jersey Center for Optoelectronics, and the Lord Corporation for support of the research described herein.

PY - 2001/3/15

Y1 - 2001/3/15

N2 - Metal alkoxides are precursors of interfacial species which can be used to enhance interactions between dissimilar components of a composite. Metal alkoxides can react with surface hydroxyl groups of metal oxides or oxidized metals to give covalently bound surface alkoxide species through protolytic loss of one or several alkoxide groups. Because of the reactivity of any remaining alkoxide ligands in the coordination sphere of these surface complexes, a variety of composites can be prepared by ligand exchange.

AB - Metal alkoxides are precursors of interfacial species which can be used to enhance interactions between dissimilar components of a composite. Metal alkoxides can react with surface hydroxyl groups of metal oxides or oxidized metals to give covalently bound surface alkoxide species through protolytic loss of one or several alkoxide groups. Because of the reactivity of any remaining alkoxide ligands in the coordination sphere of these surface complexes, a variety of composites can be prepared by ligand exchange.

KW - Metal alkoxides

KW - Metathesis

KW - Organometallic chemical vapor deposition

KW - Quartz crystal microbalance

KW - Surface organometallic chemistry

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U2 - 10.1016/S0920-5861(00)00599-X

DO - 10.1016/S0920-5861(00)00599-X

M3 - Conference article

AN - SCOPUS:0035868569

SN - 0920-5861

VL - 66

SP - 3

EP - 13

JO - Catalysis Today

JF - Catalysis Today

IS - 1

T2 - Nano-Structured Materials and Their Catalytic Funtions

Y2 - 4 December 1999 through 7 December 1999

ER -

Organometallic chemistry at the interface with materials science

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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