Optimal control of IBr curve-crossing reactions

Peter Gross; Deepa B. Bairagi; Manoj K. Mishra; Herschel Rabitz

doi:10.1016/0009-2614(94)00447-1

Optimal control of IBr curve-crossing reactions

Peter Gross, Deepa B. Bairagi, Manoj K. Mishra, Herschel Rabitz

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Control of IBr photodissociation branching ratios is explored using optimal control theory to design the requisite pulses which produce ground or spin-orbit excited bromine atoms. To conform to experimental pulse shaping limitations, these pulses are confined to a limited bandwidth and further modified by inspection of the power spectra from which extraneous frequency components are removed. Branching ratios using the filtered fields are shown to still provides appreciable selectivity, but with the added benefit of more feasible pulse shapes.

Original language	English (US)
Pages (from-to)	263-268
Number of pages	6
Journal	Chemical Physics Letters
Volume	223
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(94)00447-1
State	Published - Jun 17 1994

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(94)00447-1

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title = "Optimal control of IBr curve-crossing reactions",

abstract = "Control of IBr photodissociation branching ratios is explored using optimal control theory to design the requisite pulses which produce ground or spin-orbit excited bromine atoms. To conform to experimental pulse shaping limitations, these pulses are confined to a limited bandwidth and further modified by inspection of the power spectra from which extraneous frequency components are removed. Branching ratios using the filtered fields are shown to still provides appreciable selectivity, but with the added benefit of more feasible pulse shapes.",

author = "Peter Gross and Bairagi, {Deepa B.} and Mishra, {Manoj K.} and Herschel Rabitz",

year = "1994",

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T1 - Optimal control of IBr curve-crossing reactions

AU - Gross, Peter

AU - Bairagi, Deepa B.

AU - Mishra, Manoj K.

AU - Rabitz, Herschel

PY - 1994/6/17

Y1 - 1994/6/17

N2 - Control of IBr photodissociation branching ratios is explored using optimal control theory to design the requisite pulses which produce ground or spin-orbit excited bromine atoms. To conform to experimental pulse shaping limitations, these pulses are confined to a limited bandwidth and further modified by inspection of the power spectra from which extraneous frequency components are removed. Branching ratios using the filtered fields are shown to still provides appreciable selectivity, but with the added benefit of more feasible pulse shapes.

AB - Control of IBr photodissociation branching ratios is explored using optimal control theory to design the requisite pulses which produce ground or spin-orbit excited bromine atoms. To conform to experimental pulse shaping limitations, these pulses are confined to a limited bandwidth and further modified by inspection of the power spectra from which extraneous frequency components are removed. Branching ratios using the filtered fields are shown to still provides appreciable selectivity, but with the added benefit of more feasible pulse shapes.

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SP - 263

EP - 268

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -

Optimal control of IBr curve-crossing reactions

Abstract

All Science Journal Classification (ASJC) codes

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